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Merck
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45331

Supelco

甲基吡啶磷(甲基吡恶磷)

PESTANAL®, analytical standard

别名:

S-((6-Chloro-2-oxooxazolo[4,5-b]pyridin-3(2H)-yl)methyl) O,O-dimethyl phosphorothioate

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About This Item

经验公式（希尔记法）:
C9H10ClN2O5PS
CAS号:
35575-96-3
分子量:
324.68
EC 号:
252-626-0
MDL编号:
MFCD00867611
UNSPSC代码:
41116107
PubChem化学物质编号:
329756653
NACRES:
NA.24

等级

analytical standard

质量水平

100

产品线

PESTANAL®

保质期

limited shelf life, expiry date on the label

技术

HPLC: suitable
gas chromatography (GC): suitable

应用

agriculture
environmental

包装形式

neat

储存温度

2-8°C

SMILES字符串

COP(=O)(OC)SCN1C(=O)Oc2cc(Cl)cnc12

InChI

1S/C9H10ClN2O5PS/c1-15-18(14,16-2)19-5-12-8-7(17-9(12)13)3-6(10)4-11-8/h3-4H,5H2,1-2H3

InChI key

VNKBTWQZTQIWDV-UHFFFAOYSA-N

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相关类别

一般描述

Azamethiphos is classified under the heterocyclic organothiophosphate group of compounds.

应用

Azamethiphos may be used as an analytical reference standard for the determination of azamethiphos in:
  • Salmon feed samples by ultra-high performance liquid chromatography combined with traveling-wave ion mobility/quadrupole time-of-flight mass spectrometry (UHPLC-TWIMS-QTOFMS).
  • Surface water samples by solid-phase extraction (SPE) and LC coupled to quadrupole-Orbitrap high resolution tandem mass spectrometry (Q-Orbitrap-MS).
  • Fish fillet samples by QuEChERS (quick, easy, cheap, effective, rugged and safe) extraction and LC-QTOFMS.
  • Human serum samples by QuEChERS combined with LC coupled to tandem mass spectrometry (MS/MS).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

推荐产品

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

法律信息

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

警示用语：

Danger

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Skin Sens. 1 - STOT SE 1

靶器官

Nervous system

储存分类代码

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCF3468
BCBV5727
BCBS0605V

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Anna C Khot et al.
Pest management science, 64(11), 1139-1142 (2008-05-16)
Conventional in vitro assays sometimes fail to reveal esterase inhibition by piperonyl butoxide (PBO), although synergism studies suggest loss of esterase-mediated sequestration of insecticide does take place. A new in vitro assay has been devised that routinely reveals binding between
Multi-residue analysis of pesticides in surface water by liquid chromatography quadrupole-Orbitrap high resolution tandem mass spectrometry.
Casado J, et al.
Analytica Chimica Acta, 1024, 1-17 (2018)
Marie L Hannam et al.
Environmental pollution (Barking, Essex : 1987), 152(2), 342-350 (2007-07-28)
Here, we identify and characterise cholinesterase (ChE) and carboxylesterase (CbE) activities in the body tissues of the sediment dwelling worm Arenicola marina. Exposure to the organophosphorus pesticide azamethiphos yielded an in vitro IC50 of 5 microg l(-1) for propionylcholinesterase (PChE).
Sükran Cakir et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 43(3), 443-450 (2005-02-01)
In this study, different concentrations of some organophosphate insecticides (methyl parathion, azamethiphos, dichlorvos and diazinon) have been evaluated for genotoxicity in the wing somatic mutation and recombination test (SMART) of Drosophila melanogaster. Third-instar larvae trans-heterozygous for two genetic markers mwh
Michael Kristensen et al.
Pest management science, 62(8), 738-745 (2006-05-24)
Anti-cholinesterase resistance is in many cases caused by modified acetylcholinesterase (MACE). A comparison was made of toxicological data and AChE activity gathered from 21 field populations and nine laboratory strains of houseflies, Musca domestica L., to elucidate the best way
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实验方案

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Testing Food for Fipronil Contamination

Test your food for fipronil contamination using our analytical standards, certified reference materials, solvents, and columns for analysis.

Testing Food for Fipronil Contamination

Test your food for fipronil contamination using our analytical standards, certified reference materials, solvents, and columns for analysis.

Testing Food for Fipronil Contamination

Test your food for fipronil contamination using our analytical standards, certified reference materials, solvents, and columns for analysis.

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