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Merck
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文件

310328

Sigma-Aldrich

碳酸丙烯酯

anhydrous, 99.7%

别名:

1,2-丙二醇碳酸酯, 4-甲基-1,3-二氧戊环-2-酮

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About This Item

经验公式（希尔记法）:
C4H6O3
CAS号:
108-32-7
分子量:
102.09
Beilstein:
107913
EC號碼:
203-572-1
MDL號碼:
MFCD00005385
分類程式碼代碼:
12352005
PubChem物質ID:
57648504
NACRES:
NA.21

等級

anhydrous

品質等級

100

蒸汽壓力

0.13 mmHg ( 20 °C)
0.98 mmHg ( 50 °C)

化驗

99.7%

形狀

liquid

自燃溫度

851 °F

expl. lim.

14.3 %

雜質

<0.002% water
<0.005% water (100 mL pkg)

折射率

n20/D 1.421 (lit.)

pH值

7 (20 °C, 200 g/L)

bp

240 °C (lit.)

mp

−55 °C (lit.)

密度

1.204 g/mL at 25 °C (lit.)

SMILES 字串

CC1COC(=O)O1

InChI

1S/C4H6O3/c1-3-2-6-4(5)7-3/h3H,2H2,1H3

InChI 密鑰

RUOJZAUFBMNUDX-UHFFFAOYSA-N

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相关类别

一般說明

碳酸丙烯酯可由环氧丙烷和CO2合成。光学活性形式的碳酸丙烯酯可通过CO2 与外消旋环氧化物的反应进行制备。在锂电池的石墨电极上分解碳酸丙烯酯，可形成嵌锂化合物。
碳酸丙烯酯是一种环状碳酸酯，通常被用作有机合成的溶剂和反应性中间体。由于碳酸丙烯酯具有低蒸气压、高介电常数和高化学稳定性，它被认为是一种潜在的电化学溶剂。

應用

碳酸丙烯酯可用作非官能化烯烃的不对称加氢反应的溶剂。

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H319

危險分類

Eye Irrit. 2

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 1

閃點（°F）

269.6 °F - closed cup

閃點（°C）

132 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

从最新的版本中选择一种：

分析证书(COA)

Lot/Batch Number
SHBS0083
SHBR7868
SHBR4866
SHBR8374
SHBQ9986

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Catalytic performance of metal oxides for the synthesis of propylene carbonate from urea and 1, 2-propanediol.
Li Q, et al.
J. Mol. Catal. A: Chem., 270(1), 44-49 (2007)
Hajime Kawanami et al.
Chemical communications (Cambridge, England), (7)(7), 896-897 (2003-05-13)
The synthesis of propylene carbonate from propylene oxide and carbon dioxide under supercritical conditions in the presence of 1-octyl-3-methylimidazolium tetrafluoroborate was achieved in nearly 100% yield and 100% selectivity within 5 minutes, whose TOF value is 77 times larger than
Vincenza Modafferi et al.
Nanomaterials (Basel, Switzerland), 10(8) (2020-08-19)
The effect of the type of dopant (titanium and manganese) and of the reduced graphene oxide content (rGO, 30 or 50 wt %) of the α-Fe2O3@rGO nanocomposites on their microstructural properties and electrochemical performance was investigated. Nanostructured composites were synthesized
Michael L Aubrey et al.
Nature materials, 17(7), 625-632 (2018-06-06)
Conductive metal-organic frameworks are an emerging class of three-dimensional architectures with degrees of modularity, synthetic flexibility and structural predictability that are unprecedented in other porous materials. However, engendering long-range charge delocalization and establishing synthetic strategies that are broadly applicable to
The cathodic decomposition of propylene carbonate in lithium batteries.
Arakawa M and Yamaki JI.
Journal of Electroanalytical Chemistry, 219(1-2), 273-280 (1987)
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