1.09671

1,4-Dioxane

for analysis EMSURE^® ACS,ISO

• 别名: 1,4-Dioxane, Glycolethylether, 1,4-Diethylene dioxide, 1,4-Dioxacyclohexane
• 经验公式（希尔记法）: C₄H₈O₂
• CAS号: 123-91-1
• 分子量: 88.11
• MDL號碼: MFCD00006571
• 分類程式碼代碼: 12191504
• 酶委員會索引編號: 204-661-8
• NACRES: NB.21

属性

• 等級: ACS reagent
• 品質等級: 300
• agency: reag. ISO
• 蒸汽壓力: 41 hPa ( 20 °C)
• 產品線: EMSURE^®
• 化驗: ≥99.5% (GC)
• 形狀: liquid
• 自燃溫度: 300 °C
• 效力: 5200 mg/kg LD₅₀, oral (Rat); 7600 mg/kg LD₅₀, skin (Rabbit)
• expl. lim.: 1.7-25.2 % (v/v)
• 雜質: ≤0.0008 meq/g Acidity; ≤0.005% Acetaldehyde; ≤0.005% Peroxide (as H₂O₂); ≤0.01% Carbonyl compounds (as CO); ≤0.05% Formaldehyde; ≤0.05% Water
• 蒸發殘留物: ≤0.001%
• 顏色: APHA: ≤10
• pH值: 6-8 (20 °C, 500 g/L in H₂O)
• bp: 101.5 °C/1013 hPa
• mp: 12 °C
• 轉變溫度: flash point 11 °C
• 密度: 1.03 g/cm³ at 20 °C
• 正離子痕跡: Al: ≤0.00005%; B: ≤0.000002%; Ba: ≤0.00001%; Ca: ≤0.00005%; Cd: ≤0.000005%; Co: ≤0.000002%; Cr: ≤0.000002%; Cu: ≤0.000002%; Fe: ≤0.00001%; Mg: ≤0.00001%; Mn: ≤0.000002%; Ni: ≤0.000002%; Pb: ≤0.00001%; Sn: ≤0.00001%; Zn: ≤0.00001%
• 儲存溫度: 2-30°C
• InChI: 1S/C4H8O2/c1-2-6-4-3-5-1/h1-4H2
• InChI 密鑰: RYHBNJHYFVUHQT-UHFFFAOYSA-N

说明

一般說明

EMSURE grade solvents are suitable for a broad spectrum of classical lab applications, and are frequently used in regulated and highly demanding lab applications. EMSURE provides worldwide best and most extensive product specifications. We declare our EMSURE range to be in compliance with the ACS, with the reagent part of the European Pharmacopoeia (Reag. Ph Eur) and also with the ISO standards.

應用

• Preferential Solvation Phenomena as Solute-Induced Structure-Making/Breaking Processes: Linking Thermodynamic Preferential Interaction Parameters to Fundamental Structure Making/Breaking Functions.: This study explores the solvation dynamics and interactions in solutions containing 1,4-dioxane, highlighting the solute′s influence on molecular arrangements and interactions (Chialvo AA, 2024).


• Green Synthesis of Highly Fluorescent NCQDs: A Comprehensive Study on Synthesis, Characterization, Photophysical Properties, pH Sensing, Heavy Metal Detection, and Solvatochromic Behavior through Hydrothermal Method.: Discusses the development of nanocrystals using 1,4-dioxane as a solvent, focusing on their application in environmental monitoring and chemical sensing (Negi P et al., 2024).


• Concentration Fluctuation/Microheterogeneity Duality Illustrated with Aqueous 1,4-Dioxane Mixtures.: This paper presents a theoretical analysis of the mixture behavior of water and 1,4-dioxane, providing insights into the molecular interactions and solution properties (Kolaříková A et al., 2024).


• Synthesis, molecular docking studies and biological evaluation of N-(4-oxo-2-(trifluoromethyl)-4H-chromen-7-yl) benzamides as potential antioxidant, and anticancer agents.: Explores the synthesis of new compounds using 1,4-dioxane and their potential as therapeutic agents, highlighting the versatility of 1,4-dioxane in drug development (Jorepalli S et al., 2024).

分析報告

Purity (GC): ≥ 99.5 %
Identity (IR): conforms
Color: ≤ 10 Hazen
Acidity: ≤ 0.0008 meq/g
Density (d 20 °C/ 4 °C): 1.030 - 1.035
Melting point: ≥ 11.0 °C
Formaldehyde: ≤ 0.05 %
Acetaldehyde: ≤ 0.005 %
Peroxide (as H₂O₂): ≤ 0.005 %
Carbonyl compounds (as CO): ≤ 0.01 %
Evaporation residue: ≤ 0.001 %
Water: ≤ 0.05 %
Al (Aluminium): ≤ 0.00005 %
B (Boron): ≤ 0.000002 %
Ba (Barium): ≤ 0.00001 %
Ca (Calcium): ≤ 0.00005 %
Cd (Cadmium): ≤ 0.000005 %
Co (Cobalt): ≤ 0.000002 %
Cr (Chromium): ≤ 0.000002 %
Cu (Copper): ≤ 0.000002 %
Fe (Iron): ≤ 0.00001 %
Mg (Magnesium): ≤ 0.00001 %
Mn (Manganese): ≤ 0.000002 %
Ni (Nickel): ≤ 0.000002 %
Pb (Lead): ≤ 0.00001 %
Sn (Tin): ≤ 0.00001 %
Zn (Zinc): ≤ 0.00001 %
Stabilized with 25 ppm 2,6-Di-tert-butyl-4-methylphenol (BHT).
ACS, ISO-reagent

法律資訊

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany

安全信息

• 象形圖: GHS02,GHS07,GHS08
• 訊號詞: Danger
• 危險聲明: H225 - H319 - H335 - H350
• 防範說明: P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313
• 危險分類: Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 安全危害: EUH019 - EUH066
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 51.8 °F - closed cup
• 閃點（°C）: 11 °C - closed cup