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品質等級
化驗
96%
反應適用性
reagent type: oxidant
mp
197-199 °C (lit.)
儲存溫度
2-8°C
SMILES 字串
N#CC(C#N)=C(C#N)C#N
InChI
1S/C6N4/c7-1-5(2-8)6(3-9)4-10
InChI 密鑰
NLDYACGHTUPAQU-UHFFFAOYSA-N
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應用
用于聚苯乙炔衍生物的后官能化加成,以改变透氧性
作为以下反应的反应物:
作为以下反应的反应物:
- 区域选择性[2+2]环加成反应,用于生产BODIPY染料 和TCBD衍生物
- 与炔的热力加成反应
- 与亲核试剂的一锅法反应,形成芳香族氰基乙烯基化合物
- 合成四氰乙烯钴薄膜
- 通过灰霉菌(Botrytis cinerea)进行生物转化
訊號詞
Danger
危險聲明
危險分類
Acute Tox. 1 Oral - Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation
儲存類別代碼
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Journal of the American Chemical Society, 130(34), 11430-11436 (2008-08-06)
We report the surfactant-directed assembly of mesoporous metal/germanium-based semiconducting materials from coupling of anionic (Ge 9) (4-) clusters with various linking metal ions. The resulting materials feature a metal/Ge 9 framework perforated by regular arrays of mesoporous channels. The permanent
Chemphyschem : a European journal of chemical physics and physical chemistry, 15(17), 3776-3781 (2014-09-13)
The crystal structure of pentamethylbenzene has been obtained for the first time with the use of synchrotron radiation, whilst the low-energy spectrum of lattice dynamics, dominated by the methyl group torsions, was obtained using inelastic neutron scattering. The effect of
Chemistry (Weinheim an der Bergstrasse, Germany), 14(25), 7638-7647 (2008-07-22)
A series of monomeric and oligomeric donor-substituted 1,1,4,4-tetracyanobuta-1,3-dienes (TCBDs) with various topologies have been synthesized by means of thermal [2+2] cycloaddition between tetracyanoethylene (TCNE) and donor-substituted alkynes, followed by retro-electrocyclization. One-electron-reduced and -oxidized stages of the donor-substituted TCBDs were generated
Click-type reaction of aromatic polyamines for improvement of thermal and optoelectronic properties.
Journal of the American Chemical Society, 130(43), 14074-14075 (2008-10-07)
A quantitative addition reaction between aromatic amino-substituted alkynes and tetracyanoethylene (TCNE), yielding donor-substituted tetracyanobutadiene chromophores, was for the first time employed as a click-type reaction to improve the thermal and optoelectronic properties of aromatic polyamines. The first reduction potentials or
Organic letters, 13(3), 474-477 (2010-12-22)
Complex tetracyclic ring systems were assembled by a photoinduced rearrangement of 3,3'-bis(arylbenzofurans). Irradiation of 1 under N(2) atmosphere yielded the benzonaphthofurans 2 in 75-90% yield. When the reaction was conducted under an O(2) atmosphere in the presence of tetracyanoethylene (TCNE)
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