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Merck

S5006

Sigma-Aldrich

氧化苯乙烯

97%

别名:

1,2-环氧乙基苯, 环氧苯乙烷, 苯基环氧乙烷

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About This Item

经验公式(希尔记法):
C8H8O
CAS号:
分子量:
120.15
Beilstein:
108582
EC號碼:
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23

蒸汽密度

4.14 (vs air)

蒸汽壓力

<1 mmHg ( 20 °C)

化驗

97%

自燃溫度

928 °F

expl. lim.

~22 %

折射率

n20/D 1.535 (lit.)

bp

194 °C (lit.)

mp

−37 °C (lit.)

密度

1.054 g/mL at 25 °C (lit.)

SMILES 字串

C1OC1c2ccccc2

InChI

1S/C8H8O/c1-2-4-7(5-3-1)8-6-9-8/h1-5,8H,6H2

InChI 密鑰

AWMVMTVKBNGEAK-UHFFFAOYSA-N

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應用

  • 用锡催化剂合成不同分子量的聚(苯乙烯氧化物):本研究探索了苯乙烯氧化物的开环聚合,使用锡催化剂生产不同分子量的均聚物(Kayan, 2015)。
  • 由四氟硼酸盐基离子液体电生成BF3:选择性氧化苯乙烯异构化的理论和实验研究:利用电生成的BF3选择性异构化氧化苯乙烯的研究,强调了理论和实验见解(Bortolami et al., 2021)。
  • 非贵金属催化剂级联反应中氧化苯乙烯选择性转化为2-苯乙醇的研究:本文研究了使用非贵金属催化剂将氧化苯乙烯催化转化为2-苯乙醇的方法(Sasu et al., 2016)。
  • 芳香族手性分子星际搜索的实验室蓝图:苯乙烯氧化物的旋转特征:用于星际空间潜在探测的苯乙烯氧化物旋转光谱研究(Stahl et al., 2020)。

象形圖

Skull and crossbonesHealth hazard

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Carc. 1B - Eye Irrit. 2 - Muta. 1B - Skin Irrit. 2 - Skin Sens. 1

儲存類別代碼

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

176.0 °F - closed cup

閃點(°C)

80 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Jan Volmer et al.
Applied and environmental microbiology, 80(20), 6539-6548 (2014-08-17)
The application of whole cells as biocatalysts is often limited by the toxicity of organic solvents, which constitute interesting substrates/products or can be used as a second phase for in situ product removal and as tools to control multistep biocatalysis.
E E McConnell et al.
Critical reviews in toxicology, 24 Suppl, S49-S55 (1994-01-01)
Eleven long-term toxicity studies were reviewed on styrene and five on styrene oxide in an effort to evaluate the potential carcinogenic activity of these chemicals in animals. The styrene studies included inhalation exposure (rats, mice, guinea pigs, and rabbits), intragastric
The genetic toxicology of styrene and styrene oxide.
R Barale
Mutation research, 257(2), 107-126 (1991-03-01)
Shuangjun Lin et al.
Organic letters, 12(17), 3816-3819 (2010-08-14)
Neocarzinostatin (1) biosynthesis is proposed to involve a vicinal diol intermediate. It is reported that NcsF2, one of two epoxide hydrolases encoded by the NCS gene cluster, catalyzes regiospecific addition of H(2)O to C-2 of both (R)- and (S)-styrene oxides
Guang-Peng Wu et al.
Journal of the American Chemical Society, 134(42), 17739-17745 (2012-09-29)
Selective transformation of carbon dioxide and epoxides into degradable polycarbonates (CO(2)-based copolymer) has been regarded as a most promising green polymerization process. Although tremendous progress has been made during the past decade, very few successful examples have been reported to

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