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![双环[3.3.1]壬基-9-酮 ≥98%](/deepweb/assets/sigmaaldrich/product/structures/270/852/60661ded-13fb-4fc7-af36-a381880070a5/640/60661ded-13fb-4fc7-af36-a381880070a5.png)
品質等級
化驗
98%
形狀
crystals
bp
168-172 °C (lit.)
mp
93-96 °C (lit.)
SMILES 字串
O=C1C[C@@H]2CC[C@H]1C2
InChI
1S/C7H10O/c8-7-4-5-1-2-6(7)3-5/h5-6H,1-4H2/t5-,6+/m1/s1
InChI 密鑰
KPMKEVXVVHNIEY-RITPCOANSA-N
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J R Collins et al.
The Journal of biological chemistry, 263(7), 3164-3170 (1988-03-05)
The hydroxylations of d-camphor, norcamphor, pericyclocamphanone, and 5,5-difluorocamphor by cytochrome P-450cam have been examined using theoretical methods to identify and characterize properties which determine product specificity. Experimental results indicate that each molecule is hydroxylated with quite different regio-specificity when metabolized
M B Bass et al.
Proteins, 13(1), 26-37 (1992-05-01)
While cytochrome P-450cam catalyzes the hydroxylation of camphor to 5-exo-hydroxycamphor with 100% stereospecificity, norcamphor is hydroxylated by this enzyme yielding 45% 5-exo-, 47% 6-exo-, and 8% 3-exo-hydroxynorcamphor (Atkins, W.M., Sligar, S.G., J. Am. Chem. Soc. 109:3754-3760, 1987). The present study
Marko D Mihovilovic et al.
ChemSusChem, 1(1-2), 143-148 (2008-07-09)
Recombinant Escherichia coli cells expressing monooxygenases of different bacterial origin were evaluated in microbial Baeyer-Villiger oxidations of racemic fused ketones. During the enzymatic oxidation process, both the "normal" lactone generated by migration of the more-substituted carbon atom and/or the "abnormal"
Megan C Thielges et al.
The journal of physical chemistry. A, 115(34), 9714-9723 (2011-06-09)
Progress in the field of 2D IR vibrational spectroscopy has been bolstered by the production of intense mid-IR laser pulses. As higher-energy pulses are employed, a concomitant increase occurs in the likelihood of fifth-order contributions to the 2D IR spectra.
J Contzen et al.
Biochemistry, 37(13), 4317-4324 (1998-04-29)
Step-scan time-resolved Fourier transform infrared spectroscopy with a time resolution of 5 micros was applied to the carbon monoxide complex of cytochrome P-450cam (CYP101) to study the bimolecular ligand-rebinding process after flash photolysis. Spectral changes in the CO ligand stretch
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