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化驗
96%
形狀
powder
bp
180-190 °C/2 mmHg (lit.)
mp
60-64 °C (lit.)
SMILES 字串
Brc1cc2ccccc2c3ccccc13
InChI
1S/C14H9Br/c15-14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9H
InChI 密鑰
RSQXKVWKJVUZDG-UHFFFAOYSA-N
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一般說明
9-bromophenanthrene is a versatile halogenated organic compound that can be used as a reagent in various reactions such as Friedel-Crafts reaction and the Diels-Alder reaction. It is also used as a precursor for the synthesis of 9-bromoanthracene, 9-bromophenanthroline, and 9-bromophenanthridine.
應用
9-bromophenanthrene can be used as a building block in the synthesis of N-heterocyclic-carbene complexes via Suzuki−Miyaura cross-coupling reaction with aryl boronic acids.
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
其他客户在看
Diels-Alder Addition of N, N-Diethyl-1, 3-butadienylamine to Dehydroaromatic Intermediates Generated from Some Haloaromatics (Commemoration Issue Dedicated to Professor Tatsuo Yamamoto on the Occasion of his Retirement)
Bulletin of the Institute of Maritime and Tropical Medicine in Gdynia, 58, 289-292 (1980)
Aryne cycloaddition reactions in the synthesis of large polycyclic aromatic compounds
European Journal of Organic Chemistry, 2013, 5981-6013 (2013)
N-heterocyclic-carbene complexes readily prepared from di-$\mu$-hydroxopalladacycles catalyze the Suzuki arylation of 9-bromophenanthrene
Organometallics, 34, 522-533 (2005)
Synthesis of 9, 9?-biphenanthryl-10, 10?-bis (oxazoline) s and their preliminary evaluations in the Friedel-Crafts alkylations of indoles with nitroalkenes
Tetrahedron, 65, 1010-1016 (2009)
Charge-transfer complexes of brominated polycyclic aromatic hydrocarbons
Australian Journal of Chemistry, 15, 278-289 (1962)
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