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品質等級
化驗
40-50% Ru basis (gravimetric)
99.99% trace metals basis
形狀
powder
specific gravity measuring range
6.97 g/mL
雜質
≤150 ppm (trace metals analysis)
顏色
dark gray to black
pH值
1-2
溶解度
water: soluble
密度
3.11 g/mL at 25 °C (lit.)
SMILES 字串
Cl[Ru](Cl)Cl
InChI
1S/3ClH.Ru/h3*1H;/q;;;+3/p-3
InChI 密鑰
YBCAZPLXEGKKFM-UHFFFAOYSA-K
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一般說明
Ruthenium chloride is a dark brown or black solid often used as a powder. It is slightly soluble in organic solvents. Typically, ruthenium metal powder and chlorine are heated to create anhydrous ruthenium(III) chloride.
應用
Ruthenium chloride is most used as a precursor for the synthesis of ruthenium complexes. One common application of ruthenium trichloride is in the synthesis of ruthenium nanoparticles, which are used as catalysts or composited with other materials and used as co-catalysts for both oxygen and hydrogen evolution reactions Researchers have used our ruthenium chloride to produce high-quality, catalytically active ruthenium nanoparticles and ruthenium oxide nanoparticles. In addition, common application of ruthenium chloride anhydrous is as a precursor for single-atom catalysts. For example, scientists have used ruthenium chloride for the synthesis of ruthenium single-atom-doped ZrO2 particles to catalyze nitrogen fixation and for the synthesis of ruthenium single-atom-doped MXenes to catalyze hydrogen evolution. A third common application of ruthenium chloride hydrate is in the synthesis of metal alloys, like PtRuIr, or PtRuFe, which are investigated for electrocatalysis, usually the oxidation of simple organics like methanol or formic acid.
訊號詞
Danger
危險聲明
危險分類
Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
Nitrogen Fixation by Ru Single-Atom Electrocatalytic Reduction
Tao H, et al.
Chem, 5, 204-214 (2019)
Tailoring the composition of ultrathin, ternary alloy PtRuFe nanowires for the methanol oxidation reaction and formic acid oxidation reaction
Scofield M E, et al.
Energy & Environmental Science, 8, 350-363 (2015)
Vinoth Ramalingam et al.
Advanced materials (Deerfield Beach, Fla.), 31(48), e1903841-e1903841 (2019-10-18)
A titanium carbide (Ti3 C2 Tx ) MXene is employed as an efficient solid support to host a nitrogen (N) and sulfur (S) coordinated ruthenium single atom (RuSA ) catalyst, which displays superior activity toward the hydrogen evolution reaction (HER).
Youngmin Lee et al.
The journal of physical chemistry letters, 3(3), 399-404 (2012-02-02)
The activities of the oxygen evolution reaction (OER) on iridium-oxide- and ruthenium-oxide-based catalysts are among the highest known to date. However, the OER activities of thermodynamically stable rutile iridium oxide (r-IrO2) and rutile iridium oxide (r-RuO2), normalized to catalyst mass
Javeed Mahmood et al.
Nature nanotechnology, 12(5), 441-446 (2017-02-14)
The hydrogen evolution reaction (HER) is a crucial step in electrochemical water splitting and demands an efficient, durable and cheap catalyst if it is to succeed in real applications. For an energy-efficient HER, a catalyst must be able to trigger
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