900943

氯(4-氰基苯基)[(R)-1-[(S)-2-(二环己基膦基)二茂铁基]乙基二环已基膦]镍(II)

• 别名: SK-J003-1n
• 经验公式（希尔记法）: C₄₃H₆₀ClFeNNiP₂
• CAS号: 2049086-35-1
• 分子量: 802.88
• 分類程式碼代碼: 12352103
• NACRES: NA.22

属性

• 形狀: powder or solid
• 品質等級: 100
• 反應適用性: core: nickel; reaction type: Cross Couplings; reagent type: catalyst; reaction type: Asymmetric synthesis
• SMILES 字串: Cl[Ni+2]C1=CC=C(C#N)C=C1.C[C@@H](P(C2CCCCC2)C3CCCCC3)[C]4[C][C][C][C]4P(C5CCCCC5)C6CCCCC6.[C]7[C][C][C][C]7.[Fe]

说明

應用

Amination of aryl chlorides, bromides and sulfonates with ammonia. Amination of aryl carbamates with ammonia or ammonium salts.

其他說明

Nickel-Catalyzed Monoarylation of Ammonia
Valorization of the Primary Building Blocks Ammonia and Acetone Featuring Pd- and Ni-Catalyzed Monoarylations

安全信息

• 象形圖: GHS08,GHS07,GHS09
• 訊號詞: Warning
• 危險聲明: H315,H361d,H411
• 防範說明: P202 - P264 - P273 - P280 - P302 + P352 - P308 + P313
• 危險分類: Aquatic Chronic 2 - Repr. 2 - Skin Irrit. 2
• 儲存類別代碼: 4.1B - Flammable solid hazardous materials
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable