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Merck
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文件

794279

Sigma-Aldrich

Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)

别名:

Buchwald Nickel Cross-Coupling Catalyst Precursor, [Bis(triphenylphosphine)](o-tolyl)chloronickel

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About This Item

经验公式（希尔记法）:
C43H37ClNiP2
CAS号:
27057-09-6
分子量:
709.85
分類程式碼代碼:
12161600
PubChem物質ID:
329768436
NACRES:
NA.22

形狀

solid

品質等級

100

反應適用性

core: nickel
reagent type: catalyst

mp

195-200 °C

儲存溫度

2-8°C

SMILES 字串

Cl[Ni]C1=CC=CC=C1C.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7

InChI

1S/2C18H15P.C7H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-5H,1H3;1H;/q;;;;+1/p-1

InChI 密鑰

QVGJKVLYWZGANE-UHFFFAOYSA-M

相关类别

應用

Product is a precursor to the synthesis of an air-stable Ni-precatalyst developed by Buchwald and coworkers.

其他說明

Development of an Air-Stable Nickel Precatalyst for the Amination of Aryl Chlorides, Sulfamates, Mesylates, and Triflates

象形圖

Health hazardExclamation mark
GHS08,GHS07

訊號詞

Danger

危險聲明

H317,H350

危險分類

Carc. 1B - Skin Sens. 1

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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商品

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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