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Merck

791105

Sigma-Aldrich

Zinc chloromethanesulfinate

95% (H-NMR)

别名:

Baran MCMS Reagent

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About This Item

经验公式(希尔记法):
C2H4Cl2O4S2Zn
CAS号:
分子量:
292.48
MDL號碼:
分類程式碼代碼:
12352101
PubChem物質ID:
NACRES:
NA.22

化驗

95% (H-NMR)

形狀

solid

反應適用性

reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

reagent type: diversification reagent

mp

190-195 °C

儲存溫度

2-8°C

SMILES 字串

ClCS(O[Zn]OS(CCl)=O)=O

InChI

1S/2CH3ClO2S.Zn/c2*2-1-5(3)4;/h2*1H2,(H,3,4);/q;;+2/p-2

InChI 密鑰

HEKATMPPXNXYJU-UHFFFAOYSA-L

應用

Zinc chloromethanesulfinate (MCMS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.1

Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Journal of the American Chemical Society
O'Hara,F.; et. al.
Journal of the American Chemical Society, 135, 12122-12134 null
Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles
Fujiwara, Y.; et al.
Nature, 492, 95-100 (2013)

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