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77896

Sigma-Aldrich

1-丁基-3-甲基咪唑双(三氟甲基磺酰)酰亚胺

≥98.0% (HPLC)

别名:

BMIIm, BMIM TFSI

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About This Item

经验公式（希尔记法）:
C10H15F6N3O4S2
CAS号:
174899-83-3
分子量:
419.36
MDL编号:
MFCD05664714
UNSPSC代码:
12352100
PubChem化学物质编号:
57652686
NACRES:
NA.22

方案

≥98.0% (HPLC)

表单

liquid

杂质

≤0.5% water

折射率

n20/D 1.428

官能团

fluoro

SMILES字符串

CCCCn1cc[n+](C)c1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C8H15N2.C2F6NO4S2/c1-3-4-5-10-7-6-9(2)8-10;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h6-8H,3-5H2,1-2H3;/q+1;-1

InChI key

INDFXCHYORWHLQ-UHFFFAOYSA-N

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一般描述

1-丁基-3-甲基咪唑双(三氟甲基磺酰)酰亚胺是一种室温离子液体（RTIL）。在该离子液体中，烷烃气体的溶解度小于烯烃气体。与1-丁基-3-甲基咪唑二氰胺相比，其溶解CO2 的能力更强。

应用

  • Application of 1-butyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide ionic liquid for different types of separations problem：研究1-丁基-3-甲基咪唑双三氟甲磺酰亚胺盐的工业分离应用，说明它对环境的好处和效用(S Singh et al., 2016, Elsevier)。

外形

离子液体

法律信息

产品受美国专利 5,827,602 保护，转让给 Covalent Associates, Inc. Woburn, MA, USA

警示用语：

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral

靶器官

Nervous system

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCL9851
BCCL0367
BCCK4242
BCCJ8397
BCCH0488

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Speciation of Uranyl Nitrato Complexes in Acetonitrile and in the Ionic Liquid 1?Butyl?3?methylimidazolium Bis (trifluoromethylsulfonyl) imide
Servaes, Kelly, et al.
European Journal of Inorganic Chemistry, 2007.32, 5120-5126 (2007)
Physicochemical properties, structure, and conformations of 1-butyl-3-methylimidazolium bis (trifluoromethanesulfonyl) imide [C4mim]NTf2 ionic liquid.
Blokhin AV, et al.
The Journal of Physical Chemistry B, 112(14), 4357-4364 (2008)
The gaseous enthalpy of formation of the ionic liquid 1-butyl-3-methylimidazolium dicyanamide from combustion calorimetry, vapor pressure measurements, and ab initio calculations
Emel'yanenko, Vladimir N., Sergey P. Verevkin, and Andreas Heintz
Journal of the American Chemical Society, 129.13, 3930-3937 (2007)
Solubilities of gases in the ionic liquid 1-n-butyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide.
Lee BC and Outcalt SL.
Journal of Chemical and Engineering Data, 51(3), 892-897 (2006)
A comparative study on the reactivity of electrogenerated bromine with cyclohexene in acetonitrile and the room temperature ionic liquid, 1-butyl-3-methylimidazolium bis [(trifluoromethyl) sulfonyl] imide
Allen, Gary D., et al.
The Journal of Physical Chemistry B, 108.41, 16322-16327 (2004)
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