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Merck

726842

Sigma-Aldrich

(R)-(+)-4-甲氧基-α-甲基苄胺

ChiPros®, produced by BASF, 99%

别名:

(R)-(+)-1-(4-甲氧基苯基)乙胺

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About This Item

经验公式(希尔记法):
C9H13NO
CAS号:
分子量:
151.21
Beilstein:
2413029
MDL號碼:
分類程式碼代碼:
12352112
PubChem物質ID:
NACRES:
NA.22

等級

produced by BASF

品質等級

化驗

≥98.5% (GC)
99%

形狀

liquid

光學純度

enantiomeric excess: ≥98.5%

密度

1.024 g/mL at 20 °C (lit.)

官能基

amine

SMILES 字串

COc1ccc(cc1)[C@@H](C)N

InChI

1S/C9H13NO/c1-7(10)8-3-5-9(11-2)6-4-8/h3-7H,10H2,1-2H3/t7-/m1/s1

InChI 密鑰

JTDGKQNNPKXKII-SSDOTTSWSA-N

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應用

(R)-(+)-4-Methoxy-α-methylbenzylamine can be used as a reactant to prepare:
  • Enantiopure stereoisomers of hemicryptophanes, which are used for the recognition of glucopyranosides.
  • Bicyclic Geissman-Waiss lactone via intramolecular ring-closure reaction of the diastereomeric mixture of sulfonium salts.
  • N-[(1R)-1-(4-Methoxyphenyl)ethyl]-N′-methylthiourea by reacting with methyl isothiocyanate.

法律資訊

ChiPros is a registered trademark of BASF SE

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1A

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析证书(COA)

Lot/Batch Number

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Improved hemicryptophane hosts for the stereoselective recognition of glucopyranosides
Schmitt A, et al.
Organic & Biomolecular Chemistry, 12(24), 4211-4217 (2014)
Synthesis of (+)-and (-)-Geissman-Waiss lactone from chiral sulfonium salts
Lopez-Gonzalez R, et al.
Tetrahedron Letters, 12(24), 151697-151697 (2020)
Yohan Park et al.
Archives of pharmacal research, 35(8), 1393-1401 (2012-09-04)
Thirty two thiourea derivatives were prepared and their agonistic activities on the retinoic acid receptor-related orphan receptor α (RORα) were evaluated. The replacement of the 3-allyl-2-imino-thiazolidin-4-one moiety of the lead compound CGP52608 (1) with various functional group substituted aromatic rings

商品

Chiral amines play an important role in stereoselective organic synthesis. They are used directly as resolving agents, building blocks, or chiral auxiliaries.

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