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Merck

710857

Sigma-Aldrich

三氯化铁 溶液

greener alternative

0.2 M in 2-methyltetrahydrofuran

别名:

氯化铁 溶液

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About This Item

线性分子式:
FeCl3
CAS号:
分子量:
162.20
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

形狀

solution

品質等級

反應適用性

core: iron
reagent type: catalyst

環保替代產品特色

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

濃度

0.2 M in 2-methyltetrahydrofuran

折射率

n20/D 1.414

密度

0.868 g/mL at 25 °C

環保替代類別

SMILES 字串

Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI 密鑰

RBTARNINKXHZNM-UHFFFAOYSA-K

一般說明

我们致力于为您带来更加绿色的替代产品,这些产品遵守一项或多项绿色化学12项原则。凭借独特的性质,如无毒、低成本、丰度高、选择性高,FeCl3可用于许多生物质转化过程。该产品在2-甲基四氢呋喃中的浓度为0.2 M,因此符合“更安全的溶剂和助剂”、“可再生原料的使用”原则,并提高了催化效率。点击此处以获取更多信息。

應用

溶于绿色溶剂2-甲基四氢呋喃 (2-MeTHF) 中的氯化铁(III)可用于:
  • 作为酚醛偶联反应的温和氧化剂
  • 用于芳基锂和酮烯醇化物的二聚体化
  • 作为一种温和的路易斯酸催化剂催化烯反应
  • Nazarov环化、迈克尔加成和丙酮化反应


2-甲基四氢呋喃(2-MeTHF): 一种生物质衍生的溶剂,广泛应用于有机化学

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2

安全危害

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

14.0 °F - closed cup

閃點(°C)

-10.0 °C - closed cup


分析证书(COA)

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Abdelwareth A O Sarhan et al.
Chemical Society reviews, 38(9), 2730-2744 (2009-08-20)
In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access
Chen-Yu Chen et al.
Clinica chimica acta; international journal of clinical chemistry, 438, 337-341 (2014-10-05)
Insulin-like growth factor binding protein-1 (IGFBP-1) constitutes a subgroup of the insulin-like growth factor binding protein systems, and its concentration in amniotic fluid is 100-1000 times higher than the concentration in other body fluids. The aim of this study was
D C Florian Wieland et al.
Colloids and surfaces. B, Biointerfaces, 109, 74-81 (2013-04-27)
The early stages of the formation of inorganic aggregates, composed of iron compounds at the solution-air interface, were investigated in situ. The properties of the solution-air interface were changed by using different Langmuir layers. In order to get insight into
Dattatraya H Dethe et al.
Organic letters, 15(3), 429-431 (2013-01-16)
A novel approach was developed for the synthesis of highly substituted indene derivatives, using an FeCl(3) catalyzed Prins-type cyclization reaction which was further applied in the total synthesis of jungianol and epi-jungianol.
Rodolphe Beaud et al.
Angewandte Chemie (International ed. in English), 51(50), 12546-12550 (2012-11-06)
IRONic electrophilic indoles! The C3-regioselective hydroarylation of N-acetyl indoles with aromatic nucleophiles mediated by FeCl(3) features a rare example of the electrophilic reactivity of the indole core in a Friedel-Crafts reaction. This indole umpolung allows us straightforward access to the

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