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About This Item
经验公式（希尔记法）:
C32H22O2
CAS号:
分子量:
438.52
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
97%
旋光性
[α]20/D -314°, c = 1 in chloroform
mp
199-203 °C
官能团
phenyl
SMILES字符串
Oc1c(c(cc2ccccc12)-c3ccccc3)-c4c(O)c5ccccc5cc4-c6ccccc6
InChI
1S/C32H22O2/c33-31-25-17-9-7-15-23(25)19-27(21-11-3-1-4-12-21)29(31)30-28(22-13-5-2-6-14-22)20-24-16-8-10-18-26(24)32(30)34/h1-20,33-34H
InChI key
NDTDVKKGYBULHF-UHFFFAOYSA-N
应用
(S)-VANOL 是一种拱形联芳基配体，可用于合成配位配合物，例如（dppe）Pt（S-VANOL）[dppe =双（二苯基膦基）乙烷]和（S,S-chiraphos）Pt （S-VANOL）[Chiraphos＝2，3-双（二苯基膦基）丁烷]。
VANOL 已被证明是催化不对称 Diels-Alder、亚胺羟醛和叠氮化反应的出色配体。
警示用语：
Danger
危险分类
Aquatic Chronic 4 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Synthesis and characterization of chiral diphosphine platinum (II) VANOL and VAPOL complexes.
Becker JJ, et al.
Organometallics, 22(16), 3245-3249 (2003)
Su Yu et al.
Organic letters, 7(3), 367-369 (2005-01-28)
[reaction: see text] In an effort to develop a synthesis of the VAPOL ligand that avoids the use of a chromium carbene complex, a route was examined that involved the annulation of a naphthalene carboxamide via the method of Snieckus.
Bao. J. et al.
Journal of the American Chemical Society, 118, 3392-3392 (1996)
Yu Zhang et al.
Organic letters, 5(11), 1813-1816 (2003-05-24)
[reaction: see text] A copper-mediated deracemization of the vaulted biaryl ligands VANOL and VAPOL can be readily achieved in the presence of (-)-spartiene. The optimal procedure involves the in situ generation of copper(II) and leads to the reproducible formation of
相关内容
The research areas of interest to the Wulff group include enantioselective catalysis, mechanisms of asymmetric catalysis, macromolecular chemistry, Fischer carbene complexes in organic synthesis and the total synthesis of natural products.
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