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Merck

641375

Sigma-Aldrich

4-氟邻苯二甲酸酐

97%

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About This Item

经验公式(希尔记法):
C8H3FO3
CAS号:
分子量:
166.11
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

97%

形狀

solid

mp

75-79 °C (lit.)

官能基

anhydride
ester
fluoro

SMILES 字串

Fc1ccc2C(=O)OC(=O)c2c1

InChI

1S/C8H3FO3/c9-4-1-2-5-6(3-4)8(11)12-7(5)10/h1-3H

InChI 密鑰

XVMKZAAFVWXIII-UHFFFAOYSA-N

一般說明

4-Fluorophthalic anhydride is a fluorinated building block commonly used in chemical synthesis for the preparation of polyimide, pesticides, herbicides, and fungicides. It can be synthesized by treating 4-chlorophthalic anhydride with potassium fluoride.

應用

4-Fluorophthalic anhydride can be used as a reactant to prepare:
  • 4-amino substituted phthalimides applicable as potential fluorescent probes and fluorescent bioactive compounds.
  • 4,4′-bis(4-fluorophthalimido)diphenyl ether monomer, which is used in the synthesis of cardo polymers via nucleophilic substitution polymerization reaction.
  • Asymmetric polyimides by a solution polycondensation reaction.

象形圖

Skull and crossbones

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis of cardo containing asymmetric poly (ether-naphthalimide-phthalimide) s
Mushtaq N, et al.
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Saturated vapor pressure of 4-fluorophthalic anhydride and 4-chlorophthalic anhydride and isobaric vapor-liquid phase equilibrium of 4-fluorophthalic anhydride+ 4-chlorophthalic anhydride: Measurement and modeling
LiRongRong, et al.
Fluid Phase Equilibria, 396, 35-42 (2015)
Synthesis of high performance phenolphthalein-based cardo poly (ether ketone imide) s via aromatic nucleophilic substitution polymerization
Liu Jiangtao, et al.
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Efficient one-step synthesis of 4-amino substituted phthalimides and evaluation of their potential as fluorescent probes
Kindahl T and Chorell E
Organic & Biomolecular Chemistry, 12(25), 4461-4470 (2014)
Vu H Nguyen et al.
EJNMMI research, 3(1), 80-80 (2013-12-18)
Sigma2 (σ2) receptors are highly expressed in cancer cell lines and in tumours. Two novel selective 18F-phthalimido σ2 ligands, 18F-SIG343 and 18F-SIG353, were prepared and characterised for their potential tumour imaging properties. Preparation of 18F-SIG343 and 18F-SIG353 was achieved via

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