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反應適用性
reaction type: Grignard Reaction
品質等級
濃度
1.0 M in diethyl ether
密度
0.863 g/mL at 25 °C
SMILES 字串
CCCCC(CC)C[Mg]Br
InChI
1S/C8H17.BrH.Mg/c1-4-6-7-8(3)5-2;;/h8H,3-7H2,1-2H3;1H;/q;;+1/p-1
InChI 密鑰
NDCJRLBSQQDNOO-UHFFFAOYSA-M
應用
(2-Ethylhexyl)magnesium bromide (Grignard reagent) can be used in the synthesis of:
- 3-ethyl-N,N-dimethyl-1-(pyridin-2-yl)heptan-1-amine, a pyridyl amine ligand, which is used in the polymerization of olefins.
- Diphenylbis(2-ethylhexyl) germane from diphenylgermanium dichloride by Grignard addition reaction.
- Dichloro (dodecyl) 2-ethylhexylsilane, a key intermediate that is used in the preparation of silafluorene-based copolymers.
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
標靶器官
Respiratory system
安全危害
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
-13.0 °F - closed cup
閃點(°C)
-25 °C - closed cup
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A series of silafluorene-based copolymers, poly[9-(2-ethylhexyl)-9-dodecyl-silafluorene-2,7-diyl-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)] (P1), poly[9-(2-ethylhexyl)-9-dodecyl-silafluorene-2,7-diyl-alt-2,5-bis-(thiophene-2-yl)thiazolo [5,4-d]thiazole] (P2), and poly[9-(2-ethylhexyl)-9-dodecyl-silafluorene-2,7-diyl-alt-5,5-(5',8'-di-2-thienyl-2,3-bis(4-octyloxyl)phenyl)quinoxaline] (P3), were synthesized and used as donor materials in polymer solar cells (PSCs). The optical, electrochemical, and photovoltaic properties of the copolymers were investigated. The results indicate that
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