394262

十八烷基氯化镁 溶液

0.5 M in THF

• 别名: Chlorooctadecylmagnesium, Octadecane, magnesium complex
• 线性分子式: CH₃(CH₂)₁₇MgCl
• CAS号: 116980-66-6
• 分子量: 313.24
• MDL號碼: MFCD00012233
• 分類程式碼代碼: 12352103
• PubChem物質ID: 24864583
• NACRES: NA.22

属性

• 品質等級: 100
• 反應適用性: reaction type: Grignard Reaction
• 濃度: 0.5 M in THF
• bp: 67 °C
• 密度: 0.906 g/mL at 25 °C
• SMILES 字串: CCCCCCCCCCCCCCCCCC[Mg]Cl
• InChI: 1S/C18H37.ClH.Mg/c1-3-5-7-9-11-13-15-17-18-16-14-12-10-8-6-4-2;;/h1,3-18H2,2H3;1H;/q;;+1/p-1
• InChI 密鑰: ONJPXWZQVLKGIU-UHFFFAOYSA-M

说明

一般說明

Octadecylmagnesium chloride is a Grignard reagent commonly used in organic synthesis for various transformations, including nucleophilic addition reactions and carbon-carbon bond formation via palladium-catalyzed alkylation and arylation reactions.

應用

Octadecylmagnesium chloride can be used for the introduction of octyl substituents on the bipyridine skeletons to prepare functionalized 4,4′-bipyridines, which are used as linkers formation of discrete metal complexes.

安全信息

• 象形圖: GHS02,GHS08,GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H225,H302,H314,H335,H351
• 防範說明: P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• 危險分類: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• 標靶器官: Respiratory system
• 安全危害: EUH014,EUH019
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 1
• 閃點（°F）: -4.0 °F - closed cup
• 閃點（°C）: -20 °C - closed cup
• 個人防護裝備: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter