382434

(S)-(-)-1,1′-联萘-2,2′-二胺

99%

• 别名: (S)-(-)-1,1′-联(2-萘胺), (S)-(-)-1,1′-联萘-2,2′-二胺, (S)-(-)-2,2′-二氨基-1,1′-联萘, (S)-(-)-DABN
• 线性分子式: H₂NC₁₀H₆C₁₀H₆NH₂
• CAS号: 18531-95-8
• 分子量: 284.35
• Beilstein: 2419071
• MDL號碼: MFCD00145204
• 分類程式碼代碼: 12352005
• PubChem物質ID: 24863896
• NACRES: NA.22

属性

• 化驗: 99%
• 光學活性: [α]20/D −157°, c = 1 in pyridine
• 光學純度: ee: 99% (HPLC)
• mp: 242-244 °C (lit.)
• SMILES 字串: Nc1ccc2ccccc2c1-c3c(N)ccc4ccccc34
• InChI: 1S/C20H16N2/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12H,21-22H2
• InChI 密鑰: DDAPSNKEOHDLKB-UHFFFAOYSA-N

说明

應用

用于合成手性内酯。

(S)-(-)-1,1′-Binaphthyl-2,2′-diamine may be used in the synthesis of (S)-(+)-N,N′-dimethyl-N,N′-bis{3-[bis-(1-methyl-2-benzimidazolyl methyl)]-amino]-propyl}-1,1′-binaphthyl-2,2′-diamine, an octadentate ligand that can form dinuclear and trinuclear copper(II) complexes. It may also be used in the synthesis of (S_a)-N-[2´-amino-(1,1´-binaphthyl)-2-yl]-4-methylbenzenesulfonamide.

安全信息

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves