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Merck
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文件

333670

Sigma-Aldrich

三(三甲基硅烷基)膦

95%

别名:

(P(TMS)3), 三(三甲基硅烷基)-膦

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About This Item

线性分子式:
[(CH3)3Si]3P
CAS号:
15573-38-3
分子量:
250.54
MDL號碼:
MFCD00015487
分類程式碼代碼:
12161700
PubChem物質ID:
24860167
NACRES:
NA.22

品質等級

100

化驗

95%

形狀

liquid

反應適用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

折射率

n20/D 1.502 (lit.)

bp

243-244 °C (lit.)

密度

0.863 g/mL at 25 °C (lit.)

官能基

phosphine

儲存溫度

2-8°C

SMILES 字串

C[Si](C)(C)P([Si](C)(C)C)[Si](C)(C)C

InChI

1S/C9H27PSi3/c1-11(2,3)10(12(4,5)6)13(7,8)9/h1-9H3

InChI 密鑰

OUMZKMRZMVDEOF-UHFFFAOYSA-N

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應用

三（三甲基硅烷基）磷化氢(P(TMS)3)可用作前体以合成：
  • 磷化铟(InP)和磷化铟镓(InGaP)纳米晶体，III-V型半导体。
  • 手性TMS-磷杂环戊烷，可进一步用于针对不对称催化合成各种二磷杂环戊烷配体。

象形圖

FlameExclamation mark
GHS02,GHS07

訊號詞

Danger

危險分類

Eye Irrit. 2 - Pyr. Liq. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 2

標靶器官

Respiratory system

儲存類別代碼

4.2 - Pyrophoric and self-heating hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Sigma-Aldrich

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Sigma-Aldrich

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磷化锌

Microwave-enhanced reaction rates for nanoparticle synthesis.
Gerbec JA, et al.
Journal of the American Chemical Society, 127(45), 15791-15800 (2005)
Houman Bahmani Jalali et al.
ACS nano, 12(8), 8104-8114 (2018-07-19)
Light-induced stimulation of neurons via photoactive surfaces offers rich opportunities for the development of therapeutic methods and high-resolution retinal prosthetic devices. Quantum dots serve as an attractive building block for such surfaces, as they can be easily functionalized to match
Yuyuan Wang et al.
ACS applied materials & interfaces, 9(36), 30297-30305 (2017-08-29)
A quantum-dot (QD)-based micelle conjugated with an anti-epidermal growth factor receptor (EGFR) nanobody (Nb) and loaded with an anticancer drug, aminoflavone (AF), has been engineered for EGFR-overexpressing cancer theranostics. The near-infrared (NIR) fluorescence of the indium phosphate core/zinc sulfide shell
Formation of high quality InP and InAs nanocrystals in a noncoordinating solvent.
Battaglia D and Peng X
Nano Letters, 2(9), 1027-1030 (2002)
Francesca Pietra et al.
Chemistry of materials : a publication of the American Chemical Society, 29(12), 5192-5199 (2017-07-15)
In this work, we demonstrate that a preferential Ga-for-Zn cation exchange is responsible for the increase in photoluminescence that is observed when gallium oleate is added to InZnP alloy QDs. By exposing InZnP QDs with varying Zn/In ratios to gallium
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