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方案
96%
折射率
n20/D 1.334 (lit.)
沸点
85-86 °C (lit.)
密度
1.26 g/mL at 25 °C (lit.)
官能团
ester
fluoro
SMILES字符串
COC(=O)C(F)F
InChI
1S/C3H4F2O2/c1-7-3(6)2(4)5/h2H,1H3
InChI key
CSSYKHYGURSRAZ-UHFFFAOYSA-N
一般描述
The gas-phase reactions of Cl atoms with methyl difluoroacetate have been investigated at 296 ± 2K and atmospheric pressure of synthetic air.
应用
Methyl difluoroacetate has been used:
- to compose the electrolyte for Lithium ion cells, also showed good inhibition of aluminum cathode current collector corrosion
- as electrolyte solvent for improvement of thermal stability in lithium-ion batteries
警示用语:
Danger
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
65.1 °F - closed cup - (own results)
闪点(°C)
18.4 °C - closed cup - (own results)
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
Methyl difluoroacetate inhibits corrosion of aluminum cathode current collector for lithium ion cells.
Kawamura T, et al.
Electrochemical and Solid-State Letters, 8(9), A459-A463 (2005)
M B Blanco et al.
Environmental science & technology, 44(7), 2354-2359 (2010-03-13)
A 1080 L environmental chamber with in situ FTIR spectroscopy detection was used to study the product distribution and the mechanism of the Cl-initiated photooxidation of a series of fluoroacetates. The gas-phase reactions of Cl atoms with ethyl trifluoroacetate (CF(3)C(O)OCH(2)CH(3))
Properties of carbon anodes and thermal stability in LiPF6/methyl difluoroacetate electrolyte.
Ihara M, et al.
Journal of the Electrochemical Society, 150(11), A1476-A1483 (2003)
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