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The vibrational spectra of aqueous solutions of methylphosphonic acid and its anions were studied. The supercritical water co-oxidation elementary reaction rate mechanism for methylphosphonic acid was also studied.
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Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
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8A - Combustible corrosive hazardous materials
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WGK 2
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>392.0 °F - Pensky-Martens closed cup
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> 200 °C - Pensky-Martens closed cup
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Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Vibrational analysis of methylphosphonic acid and its anions: I. Vibrational spectra.
Journal of Molecular Structure, 15(2), 225-236 (1973)
Co-oxidation of methylphosphonic acid and ethanol in supercritical water: II: Elementary reaction rate model.
Journal of Supercritical Fluids, 39(2), 239-245 (2006)
Janel Owens et al.
Journal of agricultural and food chemistry, 57(18), 8227-8235 (2009-08-19)
Though chemical warfare agents (CWAs) have been banned by the Chemical Weapons Convention, the threat that such chemicals may be used, including their deliberate addition to food, remains. In such matrixes, CWAs may hydrolyze to phosphonic acids, which are good
Luis Briseño-Roa et al.
Protein engineering, design & selection : PEDS, 24(1-2), 151-159 (2010-11-03)
The most lethal organophosphorus nerve agents (NA), like sarin, soman, agent-VX and Russian-VX, share a methylphosphonate moiety. Pseudomonas diminuta phosphotriesterase (PTE) catalyses the hydrolysis of methylphosphonate NA analogues with a catalytic efficiency orders of magnitude lower than that towards the
James Pratt et al.
Plant physiology, 151(3), 1646-1657 (2009-09-17)
In vivo (31)P-NMR analyses showed that the phosphate (Pi) concentration in the cytosol of sycamore (Acer pseudoplatanus) and Arabidopsis (Arabidopsis thaliana) cells was much lower than the cytoplasmic Pi concentrations usually considered (60-80 mum instead of >1 mm) and that
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