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263567

Sigma-Aldrich

1,4-双(三甲基甲硅烷基)丁二炔

98%, stable crystalline form of butadiyne

别名:

1,4-双(三甲基甲硅烷基)-1,3-丁二炔, BTMSBD

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About This Item

线性分子式:
(CH3)3SiC≡CC≡CSi(CH3)3
CAS号:
4526-07-2
分子量:
194.42
Beilstein:
1758268
MDL编号:
MFCD00009839
UNSPSC代码:
12352100
PubChem化学物质编号:
24855983
NACRES:
NA.22

方案

98%

表单

solid

折射率

n20/D 1.384 (lit.)

mp

111-113 °C (lit.)

密度

0.974 g/mL at 20 °C (lit.)

储存温度

2-8°C

SMILES字符串

C[Si](C)(C)C#CC#C[Si](C)(C)C

InChI

1S/C10H18Si2/c1-11(2,3)9-7-8-10-12(4,5)6/h1-6H3

InChI key

LBNVCJHJRYJVPK-UHFFFAOYSA-N

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相关类别

应用

1,4-Bis(trimethylsilyl)butadiyne can be used as a reagent to prepare:
  • 1,1,3,4-Tetrasilyl-substituted 1,3-butadienes or 1,1,3,4-tetrasilyl-substituted 1,2-butadienes by hydrosilylation reaction using various hydridosilanes and catalysts.
  • Glycosylated oligo(ethynylene)s using the Negishi reaction.
  • (±) Falcarinol, a polyacetylene class of fatty alcohol.

象形图

Flame
GHS02

警示用语：

Danger

危险声明

H228

预防措施声明

P210

危险分类

Flam. Sol. 1

储存分类代码

4.1B - Flammable solid hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000346582
0000346581
0000315606
0000234176
1439888V

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Hydrosilylation of 1, 4-Bis (trimethylsilyl) butadiyne and Silyl-Substituted Butenynes.
Kusumoto T, et al.
Bulletin of the Chemical Society of Japan, 65(5), 1280-1290 (1992)
A short synthesis of (+) and (-)-falcarinol
McLaughlin NP, et al.
Tetrahedron, 66, 9681-9687 (2010)
Manuel M Bentlohner et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(67), 17089-17094 (2017-09-15)
We report on the synthesis and structure, as well as on the mechanism of formation of the [Ge
Manuel M Bentlohner et al.
Angewandte Chemie (International ed. in English), 54(12), 3748-3753 (2015-02-04)
The accessibility of triads with deltahedral Zintl clusters in analogy to fullerene-linker-fullerene triads is another example for the close relationship between fullerenes and Zintl clusters. The compound {[K(2.2.2-crypt)]4[RGe9-CH=CH-CH=CH-Ge9R]}(toluene)2 (R=(2Z,4E)-7-amino-5-aza-hepta-2,4-dien-2-yl), containing two deltahedral [Ge9] clusters linked by a conjugated (1Z,3Z)-buta-1,3-dien-1,4-diyl bridge
A convenient Negishi protocol for the synthesis of glycosylated oligo (ethynylene) s
Hoheisel TN and Frauenrath H
Organic Letters, 10, 4525-4528 (2008)
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