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Merck

250090

Sigma-Aldrich

1-氟辛烷

98%

别名:

辛基氟

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About This Item

线性分子式:
CH3(CH2)7F
CAS号:
分子量:
132.22
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

形狀

liquid

折射率

n20/D 1.396 (lit.)

bp

142-146 °C (lit.)

密度

0.814 g/mL at 25 °C (lit.)

官能基

alkyl halide

SMILES 字串

CCCCCCCCF

InChI

1S/C8H17F/c1-2-3-4-5-6-7-8-9/h2-8H2,1H3

InChI 密鑰

DHIVLKMGKIZOHF-UHFFFAOYSA-N

一般說明

1-Fluorooctane undergoes C-F bond-cleavage reaction with phenyl magnesium chloride to give n-octylbenzene. It reacts rapidly with trimethylsilyl iodide to give corresponding octyl iodides and trimethylsilyl fluoride.

應用

1-Fluorooctane has been used as a molecular probe in evaluations of gas chromatographic stationary phases consisting of bromo- and chloro-derivatives of a C78 branched alkane.

象形圖

FlameExclamation mark

訊號詞

Warning

危險分類

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

107.6 °F - closed cup

閃點(°C)

42 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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分析证书(COA)

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Kouki Matsubara et al.
Organic letters, 11(8), 1765-1768 (2009-03-14)
An unexpected C-F bond-cleavage reaction of unactivated fluoroalkanes with the well-known Grignard reagents without using metal catalysts has been discovered. For example, a reaction between 1-fluorooctane and phenyl magnesium chloride gave n-octylbenzene in moderate yield. This coupling reaction via the
Ervin Sz Kováts et al.
Journal of chromatography. A, 1113(1-2), 206-219 (2006-02-25)
In a paper published in 1992 [K.S. Reddy, J.-Cl. Dutoit, E.sz. Kováts, Pair-wise interactions by gas chromatography. I. Interaction free enthalpies of solutes with non-associated primary alcohol groups, J. Chromatogr. 609 (1992) 229] retention indices and standard chemical potential differences
Halogen redistribution reactions between alkyl halides and trimethylsilyl iodide.
Friedrich EC and De Lucca G.
Journal of Organometallic Chemistry, 226(2), 143-148 (1982)

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