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Merck
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文件

236306

Sigma-Aldrich

烯丙基氯

ReagentPlus®, 99%

别名:

3-氯-1-丙烯, 氯丙烯

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About This Item

线性分子式:
CH2=CHCH2Cl
CAS号:
107-05-1
分子量:
76.52
Beilstein:
635704
EC號碼:
203-457-6
MDL號碼:
MFCD00000984
分類程式碼代碼:
12352100
PubChem物質ID:
24854161
NACRES:
NA.22

蒸汽密度

2.6 (vs air)

蒸汽壓力

20.58 psi ( 55 °C)
5.71 psi ( 20 °C)

產品線

ReagentPlus®

化驗

99%

形狀

liquid

expl. lim.

11.2 %

折射率

n20/D 1.414 (lit.)

bp

44-46 °C (lit.)

mp

−130 °C (lit.)

溶解度

alcohol: miscible(lit.)
chloroform: miscible(lit.)
diethyl ether: miscible(lit.)
petroleum ether: miscible(lit.)
water: slightly soluble(lit.)

密度

0.939 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

ClCC=C

InChI

1S/C3H5Cl/c1-2-3-4/h2H,1,3H2

InChI 密鑰

OSDWBNJEKMUWAV-UHFFFAOYSA-N

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相关类别

一般說明

氯丙烯与过氧化氢环氧化的动力学过程已有报道 。

應用

氯丙烯：
  • 已用作 193 nm 激光闪光光解产生烯丙基自由基的前体
  • 已用于 α,ω-双官能团化学中间体的合成（通过 交叉复分解反应）

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

標靶器官

Nervous system,Liver,Kidney, Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 2

閃點（°F）

-25.6 °F

閃點（°C）

-32 °C

個人防護裝備

Eyeshields, Faceshields, Gloves

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Epoxidation of allyl chloride with hydrogen peroxide catalyzed by titanium silicalite 1.
Gao H, et al.
Applied Catalysis A: General, 138(1), 27-38 (1996)
Lars Seidel et al.
Molecules (Basel, Switzerland), 18(11), 13608-13622 (2013-11-07)
Photochemically driven reactions involving unsaturated radicals produce a thick global layer of organic haze on Titan, Saturn's largest moon. The allyl radical self-reaction is an example for this type of chemistry and was examined at room temperature from an experimental
Cross-metathesis reactions of allyl chloride with fatty acid methyl esters: Efficient synthesis of a, ?-difunctional chemical intermediates from renewable raw materials.
Jacobs T, et al.
Applied Catalysis A: General, 353(1), 32-35 (2009)
B M de Rooij et al.
Occupational and environmental medicine, 54(9), 653-661 (1998-01-10)
To evaluate the use of urinary mercapturic acids as a biomarker of human exposure to allyl chloride (3-chloropropene) (AC). During three regular shut down periods in a production factory for AC, both types of variables were measured in 136 workers
Qing-Shan Wang et al.
Toxicology, 227(1-2), 36-44 (2006-08-30)
Chronic exposure to allyl chloride (AC) is known to produce a central-peripheral distal axonopathy. To access the biomarker of exposure and elucidate the mechanism of neuropathy induced by AC, we performed a longitudinal observational study of malondialdehyde (MDA), anti-reactive oxygen
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