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Merck

187836

Sigma-Aldrich

1,3-二甲基金刚烷

≥99%

别名:

1,3-二甲基三环[3.3.1.13,7]癸烷

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About This Item

经验公式(希尔记法):
C12H20
CAS号:
分子量:
164.29
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥99%

形狀

liquid

折射率

n20/D 1.478 (lit.)

密度

0.886 g/mL at 25 °C (lit.)

SMILES 字串

C[C@]12C[C@@H]3C[C@H](C1)C[C@@](C)(C3)C2

InChI

1S/C12H20/c1-11-4-9-3-10(5-11)7-12(2,6-9)8-11/h9-10H,3-8H2,1-2H3/t9-,10+,11-,12+

InChI 密鑰

CWNOIUTVJRWADX-BKUVIOGVSA-N

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一般說明

1,3-二甲基金刚烷与苯基氯卡宾发生C-H插入反应。当N-羟基邻苯二甲酰亚胺和钴盐存在时,它可与氧分子反应生成3,5-二甲基金刚烷-1-醇和5,7-二甲基金刚烷-1,3-二醇

應用

1,3-二甲基金刚烷用于合成1,3-二溴-5,7-二甲基金刚烷

象形圖

Flame

訊號詞

Warning

危險聲明

危險分類

Flam. Liq. 3

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

127.4 °F - closed cup

閃點(°C)

53 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Hydroxylation of polycyclic alkanes with molecular oxygen catalyzed by N-hydroxyphthalimide (NHPI) combined with transition metal salts.
Ishii Y, et al.
Tetrahedron Letters, 37(28), 4993-4996 (1996)
The synthesis of 3-amino-3-methylbicyclo [3.3. 1] nonanes: Endo-selectivity in the Ritter reaction of 1, 3, 5, 7a-tetramethylbicyclo [3.3. 1] nonan-3-ol.
Mishnev AF.
Journal of the Chemical Society. Perkin Transactions 1, 23, 3527-3530 (1999)
R A Moss et al.
Organic letters, 1(5), 819-822 (2005-08-25)
[structure: see text] Phenylchlorocarbene inserts into the tertiary CH bonds of 1,3-dimethyladamantane and 1-X-adamantanes (X = H, OMe, COOMe, Cl, CN). There is a good correlation between the relative rate constants for these insertions and the inductive substituent constants, sigma1(X)
Nien-Hsin Kao et al.
Environmental science and pollution research international, 22(10), 7529-7546 (2015-02-26)
The sources of the spill and the contaminated soils of an aged oil spill contaminated site with unknown mixed pollutants were investigated by using a set of developed forensic chemical procedures which include analysis of oil products, site investigation, gas

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