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Merck

160687

Sigma-Aldrich

2-环庚烯-1-酮

80%, technical grade

别名:

2-Cycloheptenone, Tropilene

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About This Item

线性分子式:
C7H10(=O)
CAS号:
分子量:
110.15
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

等級

technical grade

化驗

80%

形狀

liquid

折射率

n20/D 1.494 (lit.)

密度

0.988 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

O=C1CCCCC=C1

InChI

1S/C7H10O/c8-7-5-3-1-2-4-6-7/h3,5H,1-2,4,6H2

InChI 密鑰

WZCRDVTWUYLPTR-UHFFFAOYSA-N

一般說明

2-Cyclohepten-1-one is an α,β-enone and its regioselective reaction with allyl indium reagent in the presence of TMSCl has been reported. It reacts with Bu2Zn in the presence of catalytic amounts of Cu(OTf)2 and CH2-bridged azolium salts to give (S)-3-butylcycloheptanone.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

154.4 °F - closed cup

閃點(°C)

68 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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T Masukawa et al.
Life sciences, 44(6), 417-424 (1989-01-01)
To search for a technique to deplete reduced glutathione (GSH) in brain, the influence of various types of compounds on brain GSH levels was investigated in mice. Of the compounds tested, cyclohexene-1-one, cycloheptene-1-one and diethyl maleate were shown to be
Naoatsu Shibata et al.
The Journal of organic chemistry, 77(8), 4079-4086 (2012-03-30)
A series of hydroxy-amide functionalized azolium salts have been designed and synthesized for Cu-catalyzed asymmetric conjugate addition reaction. The (CH(2))(2)-bridged hydroxy-amide functionalized azolium ligand precursors 2, in addition to the previously reported CH(2)-bridged azolium salts 1, have been prepared from
G Benzi et al.
Neurobiology of aging, 12(3), 227-231 (1991-05-01)
A severe age-dependent depletion of reduced glutathione (GSH) occurs in rat forebrain at 1-3 h from intraperitoneal injection of the electrophilic agents cyclohexene-1-one and cycloheptene-1-one. Chronic pretreatment with central dopamine agonists (i.e., ergot alkaloids; particularly, dihydroergocriptine) partially counteracts the GSH
P R Byron et al.
Journal of pharmaceutical sciences, 69(5), 527-531 (1980-05-01)
A stirred transfer cell containing equal volumes of light liquid paraffin and an aqueous phase at 37 degrees was used to demonstrate the feasibility of calculating the partition coefficient of an unstable compound by kinetic analysis. Cyclohept-2-enone was chosen since
Studies on the reactions of α, β-enones with allyl indium reagent; effects of TMSCl as promoter on regioselectivity.
Lee PH, et al.
Tetrahedron Letters, 42(1), 37-39 (2001)

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