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Supelco

MGK 264

PESTANAL®, analytical standard

Synonym(s):

N-(2-Ethylhexyl)-5-norbornene-2,3-dicarboximide

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About This Item

Empirical Formula (Hill Notation):
C17H25NO2
CAS Number:
Molecular Weight:
275.39
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

description

technical mixture of isomers

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CCCCC(CC)CN1C(=O)C2[C@H]3C[C@H](C=C3)C2C1=O

InChI

1S/C17H25NO2/c1-3-5-6-11(4-2)10-18-16(19)14-12-7-8-13(9-12)15(14)17(18)20/h7-8,11-15H,3-6,9-10H2,1-2H3/t11?,12-,13+,14?,15?

InChI key

WLLGXSLBOPFWQV-OTHKPKEBSA-N

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General description

MGK 264 is both a synergist and a mosquito repellent.

Application

MGK 264 may be used as an analytical reference standard for the determination of the target analyte in pyrethrum extracts and indoor air by various chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Skull and crossbonesEnvironment

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Skin Sens. 1B

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

350.6 °F - closed cup

Flash Point(C)

177 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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Simultaneous determination of semivolatile organic compounds in indoor air by gas chromatography-mass spectrometry after solid-phase extraction.
Yoshida T, et al.
Journal of Chromatography A, 1023(2), 255-269 (2004)
Stir bar sorptive extraction coupled to thermodesorption-gas chromatography-mass spectrometry for the determination of insect repelling substances in water samples.
Rodil R and Moeder M
Journal of Chromatography A, 1178(1-2), 9-16 (2008)
I H Wang et al.
Journal of chromatography. A, 864(2), 271-281 (2000-02-11)
N-Octyl bicycloheptene dicarboximide (MGK 264) has exo and endo diastereomers. Each structure has a chiral center at the nitrogen side chain. Enantioselective separation of MGK 264 was achieved by normal-phase high-performance liquid chromatography (HPLC) using cellulose-based Chiralcel OD column with
I-Hsiung Wang et al.
Journal of chromatography. A, 983(1-2), 145-152 (2003-02-06)
An isocratic reversed-phase high-performance liquid chromatographic (RP-HPLC) method development for the simultaneous determination of five active ingredients (S)-methoprene, MGK264, PBO, sumithrin and permethrin in a new complex pesticide formulation is described. These active ingredients have similar polarities and contain isomers.
G L Zellers et al.
Annals of emergency medicine, 19(3), 327-329 (1990-03-01)
A man experienced one hour and 40 minutes of continual, inappropriate, uncontrollable laughter. The onset was preceded by a single-inhalation exposure to an insecticide of very low toxicity. The episode was terminated by a single dose of IV diazepam. A

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