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Sigma-Aldrich

Silver carbonate

purum p.a., ≥99.0% (AT)

Synonym(s):

Disilver carbonate, Silver(I) carbonate

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About This Item

Linear Formula:
Ag2CO3
CAS Number:
Molecular Weight:
275.75
Beilstein:
6936654
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

grade

purum p.a.

Assay

≥99.0% (AT)

form

powder

reaction suitability

reagent type: catalyst
core: silver

mp

210 °C (dec.) (lit.)

density

6.08 g/mL at 25 °C (lit.)

anion traces

sulfate (SO42-): ≤500 mg/kg

cation traces

Ca: ≤50 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤100 mg/kg
Na: ≤100 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

SMILES string

[Ag]OC(=O)O[Ag]

InChI

1S/CH2O3.2Ag/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

KQTXIZHBFFWWFW-UHFFFAOYSA-L

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Application

Silver carbonate is used in Koenigs-Knorr glycosylation.

Pictograms

CorrosionEnvironment

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Roman V Rozhkov et al.
The Journal of organic chemistry, 68(16), 6314-6320 (2003-08-05)
The palladium-catalyzed annulation of 1,3-dienes by o-iodoacetoxycoumarins provides an efficient method for the synthesis of biologically interesting dihydrofurocoumarins. The presence of the acetyl group on the phenolic oxygen and the use of silver carbonate as a base are crucial for
Gregory L Hamilton et al.
Journal of the American Chemical Society, 130(45), 14984-14986 (2008-10-22)
Reactions proceeding through cationic intermediates that lack a Lewis or Brønsted basic site present a challenge for traditional asymmetric catalysis based on chiral metals or organocatalysts. We present an enantioselective ring opening of tetrasubstituted meso-aziridinium ions with alcohol nucleophiles proceeding
Palladium-catalyzed decarboxylative C-H bond arylation of thiophenes.
Peng Hu et al.
Angewandte Chemie (International ed. in English), 51(1), 227-231 (2011-11-17)
Sukalyan Bhadra et al.
Journal of the American Chemical Society, 134(24), 9938-9941 (2012-06-12)
Decarboxylative Chan-Evans-Lam-type couplings are presented as a new strategy for the regiospecific construction of diaryl and alkyl aryl ethers starting from easily available aromatic carboxylic acids. They allow converting various aromatic carboxylate salts into the corresponding aryl ethers by reaction
K Y Jan et al.
Experimental cell research, 159(1), 55-62 (1985-07-01)
Opposite differential staining between sister chromatids was obtained by two silver-staining techniques on chromosomes replicated twice in medium containing 5-bromodeoxyuridine (BrdU) and pretreated with Hoechst plus black light. Both silver-nitrate and silver-carbonate staining were affected by chemical extraction and enzyme

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