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401072

Sigma-Aldrich

Bismuth(III) bromide

≥98%

Synonym(s):

Bismuth tribromide, Tribromobismuthine

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About This Item

Empirical Formula (Hill Notation):
BiBr3
CAS Number:
7787-58-8
Molecular Weight:
448.69
EC Number:
232-121-1
MDL number:
MFCD00014195
UNSPSC Code:
12352302
PubChem Substance ID:
24864984
NACRES:
NA.23

Assay

≥98%

form

powder

reaction suitability

reagent type: catalyst
core: bismuth

density

5.7 g/mL at 25 °C (lit.)

SMILES string

Br[Bi](Br)Br

InChI

1S/Bi.3BrH/h;3*1H/q+3;;;/p-3

InChI key

TXKAQZRUJUNDHI-UHFFFAOYSA-K

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Application

Catalyzes the formation of cyclic carbonates, which are important precursors for polycarbonates and other polymeric materials.

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H314,H335

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Le Boisselier, V. et al.
Chemical Communications (Cambridge, England), 95-95 (1997)
Rui Meng et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(21), 5480-5488 (2019-02-17)
A comprehensive study unveiling the impact of heterovalent doping with Bi3+ on the structural, semiconductive, and photoluminescent properties of a single crystal of lead halide perovskites (CH3 NH3 PbBr3 ) is presented. As indicated by single-crystal XRD, a perfect cubic

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