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348104

Sigma-Aldrich

Triphenyltin hydroxide

Synonym(s):

Fentin hydroxide, Hydroxytriphenylstannane, NSC 113243

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About This Item

Linear Formula:
(C6H5)3SnOH
CAS Number:
76-87-9
Molecular Weight:
367.03
EC Number:
200-990-6
MDL number:
MFCD00013928
UNSPSC Code:
12352103
PubChem Substance ID:
24861551
NACRES:
NA.22

mp

124-126 °C (lit.)

SMILES string

O[Sn](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/3C6H5.H2O.Sn/c3*1-2-4-6-5-3-1;;/h3*1-5H;1H2;/q;;;;+1/p-1

InChI key

BFWMWWXRWVJXSE-UHFFFAOYSA-M

Application

Reactant involved in transmetalation reactions with Ir clusters

Reactant involved in synthesis of:
  • (E)-(Nitrophenyl)propenoic acid organotin(IV) carboxylates with antitumor activity
  • Triorganotin chrysanthemumates for larvicidal studies
  • Polynuclear organotin(IV) carboxylates containing ferrocenyl moieties for antitumor investigation
  • Organotin(IV) aminophenylacrylate complexes
  • 4-Biphenylcarboxylic acid derivatives for in vitro cytotoxicity studies

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 - STOT SE 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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K Grote et al.
Environmental research, 101(1), 81-88 (2005-09-16)
In a one-generation reproductive study, the fungicidal compound triphenyltin hydroxide (fentin) was administered to adult Japanese quail for 6 weeks at dietary levels of 3 and 30 ppm. Reproduction was significantly impaired in the high-dose group. The principal adverse finding
A biochromatographic technique for the quantitative estimation of triphenyltin fungicides.
M Adinarayana et al.
Journal of chromatography, 435(1), 210-218 (1988-01-01)
N Chernoff et al.
Teratology, 42(6), 651-658 (1990-12-01)
The hypothesis that chemically induced overt maternal toxicity induces a characteristic syndrome of adverse developmental effects in the rat was investigated. Pregnant animals (Sprague-Dawley strain) were dosed by oral gavage with one of a series of compounds on days 6-15
Isabella F Delgado et al.
Environmental toxicology, 24(6), 629-635 (2008-12-10)
In this study, we evaluated the effects of prenatal exposure to triphenyltin hydroxide (TPTH) on the postnatal development of Swiss Webster mice. Females were treated by gavage (0, 7.5 15 and 30 mg TPTH/kg/day) on days 6-17 of gestation. After
W H Marsh et al.
The American journal of gastroenterology, 83(10), 1158-1160 (1988-10-01)
Pancreatitis secondary to organophosphate insecticide toxicity is extremely rare. The few previously reported cases have resulted from oral ingestion of these agents. We present the first reported case of acute pancreatitis occurring after cutaneous exposure to an organophosphate insecticide. Symptoms
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