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Sigma-Aldrich

Scandium(III) oxide

99.9% trace rare earth metals basis

Synonym(s):

Discandium trioxide, Scandia, Scandium oxide, Scandium trioxide

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About This Item

Linear Formula:
Sc2O3
CAS Number:
Molecular Weight:
137.91
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Assay

99.9% trace rare earth metals basis

form

powder

reaction suitability

core: scandium
reagent type: catalyst

SMILES string

O=[Sc]O[Sc]=O

InChI

1S/3O.2Sc

InChI key

HYXGAEYDKFCVMU-UHFFFAOYSA-N

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General description

Scandium(III) oxide is a high-melting rare earth oxide that can be used as a catalyst in the dehydration of terminal diols. Furthermore, it is used as a starting material for the preparation of other scandium compounds.

Application

Scandium(III) oxide can be used as a catalyst for the dehydration of amino alcohols to unsaturated amines. It can also be used as a precursor to prepare scandium(III) trifluoromethanesulfonate, which can be used to catalyze the nitration of aromatic compounds.
Suitable for vacuum deposition applications

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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We report on the measurements of near-UV excited-state absorption (ESA) spectra and refractive index changes (RICs) in the two ytterbium doped laser crystals Yb:Lu2O3 and Yb:Sc2O3. ESA is assigned to ligand-to-metal charge transfer (LMCT) absorption transitions and RICs to the
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Physical chemistry chemical physics : PCCP, 13(21), 10084-10090 (2011-04-28)
The Sc(3)O(6)(-) cluster anions were produced by laser ablation and studied by reaction with n-butane in a fast flow reactor and by photoelectron spectroscopy. The reactivity experiments indicated that one Sc(3)O(6)(-) cluster can activate two n-butane molecules consecutively with rate

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