T0514
Trimethylamine N-oxide dihydrate
98%
Synonym(s):
TMANO
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About This Item
Linear Formula:
(CH3)3NO · 2H2O
CAS Number:
Molecular Weight:
111.14
Beilstein:
3612927
EC Number:
MDL number:
UNSPSC Code:
12352116
PubChem Substance ID:
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Assay
98%
form
powder
reaction suitability
reagent type: oxidant
mp
95-99 °C (lit.)
SMILES string
O.O.C[N+](C)(C)[O-]
InChI
1S/C3H9NO.2H2O/c1-4(2,3)5;;/h1-3H3;2*1H2
InChI key
PGFPZGKEDZGJQZ-UHFFFAOYSA-N
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Application
Reactant for:
- C-H bond cleavage
- Oxidation reactions (oxidant)
- Decarbonylating agent for solvent-free reactions
Trimethylamine N-oxide dihydrate can be used as:
- A decarbonylating agent in many chemical reactions.
- An oxidizing agent for organoboranes.
- A standard in the determination of amines in air samples using non-suppressed ion chromatography.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Oxidation of organoboranes with trimethylamine N-oxide dihydrate
Kabalka GW
Journal of Organometallic Chemistry, 125(2), 273-280 (1977)
Electrophilic attack on diphosphazane-bridged derivatives of diruthenium nonacarbonyl by halogens. Crystal structure of [Ru2 ({′A}-I) I (CO)3 {{′A}-(PriO)2 PN (Et)P (OPri)2}2]
John S, et al.
J. Chem. Soc., Dalton Trans., 10, 2761-2768 (1991)
Thermal degradation of transition metal carbonyl complexes: Part IV: Thermogravimetric studies of various stoichiometric mixtures of trimethylamine N-oxide dihydrate and hexacarbonyl molybdenum
Chan HSO, et al.
Thermochimica Acta, 145, 179-187 (1989)
Mark E Erupe et al.
Journal of chromatography. A, 1217(13), 2070-2073 (2010-02-26)
An ion chromatography method with non-suppressed conductivity detection was developed for the simultaneous determination of methylamines (methylamine, dimethylamine, trimethylamine) and trimethylamine-N-oxide in particulate matter air samples. The analytes were well separated by means of cation-exchange chromatography using a 3 mM
Hui Wei et al.
Frontiers in microbiology, 9, 3276-3276 (2019-01-29)
Yarrowia lipolytica, known to accumulate lipids intracellularly, lacks the cellulolytic enzymes needed to break down solid biomass directly. This study aimed to evaluate the potential metabolic burden of expressing core cellulolytic enzymes in an engineered high lipid-accumulating strain of Y.
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