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13468

Sigma-Aldrich

Sodium sulfide hydrate

≥60%, scales

Synonym(s):

μ-Sulfidedisodium hydrate

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About This Item

Empirical Formula (Hill Notation):
Na2S · xH2O
CAS Number:
27610-45-3
Molecular Weight:
78.04 (anhydrous basis)
EC Number:
215-211-5
MDL number:
MFCD00003498
UNSPSC Code:
12161600
PubChem Substance ID:
57647096
NACRES:
NA.22

form

scales

Quality Level

100

reaction suitability

core: sodium
reagent type: catalyst

concentration

≥60%

anion traces

chloride (Cl-): ≤100 mg/kg

storage temp.

2-8°C

SMILES string

[Na]S[Na]

InChI

1S/2Na.S

InChI key

CXPWOVUZRAFMDA-UHFFFAOYSA-N

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General description

May contain up to 40% water.

Application

Nucleophile and reducing agent derived from H2S; reagent for the synthesis of thiols, thioethers, and acyclic sulfides, di-, and polysulfides; reduces aromatic nitro compounds to amines; reduces sulfoxides to sulfides.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Supplementary Hazards

EUH031

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
STBL3845
SDBB1085
STBL2943
BCCK6303
BCCK7855

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Vanda Cerè et al.
The Journal of organic chemistry, 70(2), 664-669 (2005-01-18)
Optically pure enantiomers of the chiral tetrahydroxythiepane derivative 3,6-dihydroxy-4,5-O-isopropylidene-thiepane (3) are obtained using a novel protocol in which a library of all possible stereoisomers of 3 is synthesized, followed by two-step stereoselective chromatography, using, first, conventional achiral and, then, chiral
Total synthesis of xerulinic acid.
Achim Sorg et al.
Angewandte Chemie (International ed. in English), 43(34), 4523-4526 (2004-09-02)
Krzysztof Walczyński et al.
European journal of medicinal chemistry, 40(1), 15-23 (2005-01-12)
In search for a new lead of non-imidazole histamine H3-receptor antagonists, a series of 1[(2-thiazolopyridine)-4-n-propyl]piperazines, the analogous 1-[(2-oxazolopyridine)-4-npropyl]piperazines, 1-[(2-benzothiazole)-4-n-propyl]piperazine and 1-[(2-benzooxazole)4-n-propyl]piperazine were prepared and in vitro tested as H3-receptor antagonists (the electrically evoked contraction of the guinea-pig jejunum). It appeared
Feixiang Zan et al.
Water research, 182, 115960-115960 (2020-07-06)
Volatile fatty acids (VFAs), the intermediate of the anaerobic process, are considered to be the critical, high-sensitive and reliable indicators of the process stability. Close monitoring and control of VFAs are paramount for the efficient operation of the anaerobic reactors.
Reza Sahraei et al.
Nanotechnology, 28(47), 475604-475604 (2017-10-12)
We report here on a one-pot, mild and low cost aqueous-based synthetic route for the preparation of colloidally stable and highly luminescent dual-doped Ag,Ni:ZnCdS/ZnS core/shell quantum dots (QDs). The pure dopant emission of the Ni-doped core/shell QDs was found to
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