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Key Documents

275816

Sigma-Aldrich

cis-Bis(benzonitrile)dichloroplatinum(II)

98%

Synonym(s):

cis-Dichlorobis(benzonitrile)platinum

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About This Item

Linear Formula:
(C6H5CN)2PtCl2
CAS Number:
Molecular Weight:
472.23
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

reaction suitability

core: platinum
reagent type: catalyst

mp

224 °C (dec.) (lit.)

SMILES string

Cl[Pt]Cl.N#Cc1ccccc1.N#Cc2ccccc2

InChI

1S/2C7H5N.2ClH.Pt/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

InChI key

WAJRCRIROYMRKA-UHFFFAOYSA-L

Application

Catalyst for:
  • Asymmetric hydroformylation reactions
  • Allylation reactions
  • Carbene insertion into O-H bonds of alcohols
  • Cyclopropanation reactions
  • Hydrosilylation reactions

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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