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241776

Sigma-Aldrich

Potassium thioacetate

98%

Synonym(s):

Ethanethioic acid potassium salt, Thioacetic acid potassium salt, Thiolacetic acid potassium salt

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About This Item

Linear Formula:
CH3COSK
CAS Number:
10387-40-3
Molecular Weight:
114.21
Beilstein:
4428862
EC Number:
233-848-7
MDL number:
MFCD00137704
UNSPSC Code:
12352302
PubChem Substance ID:
24854328
NACRES:
NA.22

Assay

98%

form

solid

mp

173-176 °C (lit.)

SMILES string

[K+].CC([S-])=O

InChI

1S/C2H4OS.K/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1

InChI key

AFNBMGLGYSGFEZ-UHFFFAOYSA-M

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General description

Potassium thioacetate is a sulfur source in sulfuration reactions and is used as a reagent in nucleophilic substitution and vinylic substitution reactions.

Application

Palladium mediated coupling with aryl halides and triflates leading to S-arylthioacetates and derivatives.
Reagent in the preparation of thiols from halides.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Potassium thioacetate
Soria-Castro SM
Synlett (2012)
Tetrahedron Letters, 48, 3033-3033 (2007)
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eEROS (Encyclopedia of Reagents for Organic Synthesis), 1-8 (2001)
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