CRM74120
Triazophos
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
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About This Item
Empirical Formula (Hill Notation):
C12H16N3O3PS
CAS Number:
Molecular Weight:
313.31
Beilstein:
682554
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.24
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grade
certified reference material
TraceCERT®
Quality Level
product line
TraceCERT®
shelf life
limited shelf life, expiry date on the label
manufacturer/tradename
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
format
neat
storage temp.
−20°C
SMILES string
CCOP(=S)(OCC)Oc1ncn(n1)-c2ccccc2
InChI
1S/C12H16N3O3PS/c1-3-16-19(20,17-4-2)18-12-13-10-15(14-12)11-8-6-5-7-9-11/h5-10H,3-4H2,1-2H3
InChI key
AMFGTOFWMRQMEM-UHFFFAOYSA-N
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General description
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Triazophos― a non-systemic insecticide and acaricide, is an acetylcholinesterase (AChE) inhibitor. An organophosphate, it covalently and irreversibly reacts with the acetylcholine binding site and blocks the hydrolysis of acetylcholine, resulting in hyper excitation. Its route of action includes both ingestion and contact. Triazophos is used against soil insects and mites such as aphids, thrips, midges, beetles, Lepidoptera larvae, cutworms, and spider mites in ornamentals, cotton, rice, maize, soybeans, oil palms, olives, and coffee.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, triazophos is not approved for use in the European Union as a plant protection agent. Maximum residue limits (MRLs) applied for the presence of triazophos in food products across different countries lie in the range of 0.01 to 0.2 mg/kg.
Triazophos has to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Triazophos― a non-systemic insecticide and acaricide, is an acetylcholinesterase (AChE) inhibitor. An organophosphate, it covalently and irreversibly reacts with the acetylcholine binding site and blocks the hydrolysis of acetylcholine, resulting in hyper excitation. Its route of action includes both ingestion and contact. Triazophos is used against soil insects and mites such as aphids, thrips, midges, beetles, Lepidoptera larvae, cutworms, and spider mites in ornamentals, cotton, rice, maize, soybeans, oil palms, olives, and coffee.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, triazophos is not approved for use in the European Union as a plant protection agent. Maximum residue limits (MRLs) applied for the presence of triazophos in food products across different countries lie in the range of 0.01 to 0.2 mg/kg.
Triazophos has to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Application
The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
Triazophos CRM may find the following uses:
Triazophos CRM may find the following uses:
- Analysis of a diagnostic method for the direct monitoring of triazophos by a non-competitive surface plasmon resonance immunosensor in environmental and agricultural product samples
- Simultaneous quantitative detection of 171 pesticide residues using multi-walled carbon nanotubes (MWCNTs) as a sorbent in the reversed-dispersive solid-phase (r-DSPE) extraction of the cowpea samples followed by gas chromatographic-tandem mass spectrometric (GC-MS/MS) analysis
- Development and validation of a multi-residue method for the analysis of 160 pesticides in herbal plants samples of chamomile, thyme, and marjoram using ethyl acetate and n-hexane mixture for the extraction before GC-MS/MS direct injection
- Determination of a wide group of 250 pesticide residues in surface water samples by solid-phase extraction (SPE) and reversed-phase liquid chromatography (LC)-Orbitrap high-resolution mass spectrometry (HRMS)
- Quantifying 126 pesticide residues in chicken muscle samples using QuEChERS for sample preparation and ultra-high-performance liquid chromatography- quadrupole time-of-flight-mass spectrometry (UHPLC-QToF-MS) for subsequent analysis
Recommended products
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Legal Information
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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J Casado et al.
Analytica chimica acta, 1024, 1-17 (2018-05-20)
A quantitative targeted screening method for the determination of residues of a broad group of more than 250 pesticides in surface water samples was developed and validated. Substances were isolated from the sample matrix by solid-phase extraction (SPE), using hydrophilic-lipophilic
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