B4856
Diphenylmethanol
99%
Synonym(s):
Benzhydrol, Benzhydryl alcohol, Diphenyl carbinol
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About This Item
Linear Formula:
(C6H5)2CHOH
CAS Number:
Molecular Weight:
184.23
Beilstein:
1424379
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
99%
form
powder
bp
297-298 °C (lit.)
mp
65-67 °C (lit.)
SMILES string
OC(c1ccccc1)c2ccccc2
InChI
1S/C13H12O/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13-14H
InChI key
QILSFLSDHQAZET-UHFFFAOYSA-N
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Application
Diphenylmethanol is used in the carbene-catalyzed dynamic kinetic resolution of α,α-disubstituted carboxylic esters. It can also be used in the chiral resolution of free-base and Ni(II) porphyrinoid complexes.
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Carbene-Catalyzed Dynamic Kinetic Resolution of Carboxylic Esters.
Chen X, et al.
Journal of the American Chemical Society, 138(23), 7212-7215 (2016)
Masanori Ichikawa et al.
Bioorganic & medicinal chemistry, 19(6), 1930-1949 (2011-03-01)
To obtain small and efficient squalene synthase inhibitors, a flexible 2-aminobenzhydrol open form structure was designed and showed potent inhibitory activity comparable to 4,1-benzoxazepin compounds. Further chemical modification led to the discovery of a novel template with a strong squalene
[Determination of dimedrol and benzhydrol in the urine by high efficient liquid chromatographic method].
E N Stepanova et al.
Sudebno-meditsinskaia ekspertiza, 23(2), 40-42 (1980-04-01)
Masanori Ichikawa et al.
Bioorganic & medicinal chemistry, 19(17), 5207-5224 (2011-08-02)
We have recently reported the discovery of the new benzhydrol template, which has a highly potent inhibitory activity for squalene synthase, as typified by compound 1 (SSI IC(50)=0.85 nM). However, it was composed of a pair of easy rotatable atropisomers.
Kinetics of the hydrolysis of drugs containing the diphenyl-methyl-ether group.
O O Komolafe
Materia medica Polona. Polish journal of medicine and pharmacy, 17(2), 98-102 (1985-04-01)
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