Skip to Content
Merck
All Photos(2)

Documents

933961

Sigma-Aldrich

1,1,2,2-Tetrafluoroethyl 2,2,3,3-tetrafluoropropylether

greener alternative

≥99%, <=10 ppm acid, battery grade

Synonym(s):

1,1,2,2-Tetrafluoro-3-(1,1,2,2-tetrafluoroethoxy)propane, HFE-458, TTE

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
C5H4F8O
CAS Number:
Molecular Weight:
232.07
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21

grade

battery grade

Quality Level

description

Application: Battery manufacturing

Assay

≥99%

form

liquid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

≤10 ppm Acid
≤100 ppm Non-volatile residue
≤750 ppm H2O

bp

92 °C

density

1.54 g/mL

application(s)

battery manufacturing

greener alternative category

General description

Our 1,1,2,2-tetrafluoroethyl 2,2,3,3-tetrafluoropropylether (TTE) is a high-purity, battery-grade fluorinated ether commonly used as an electrolyte solvent in lithium-ion batteries (LIBs). It is a clear liquid with a boiling point of 92 °C that is miscible with many polar organic solvents, including carbonates typically used in battery electrolytes. Our TTE is produced to meet the high standards of battery-grade purity, ensuring a minimum purity level of 99%, and is carefully purified to become anhydrous and acid-free, making it a reliable choice for battery applications.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

Application

1,1,2,2-Tetrafluoroethyl 2,2,3,3-tetrafluoropropylether (TTE) is a highly versatile fluorinated ether that finds its use as a co-solvent and additive in a range of battery systems, including lithium-sulfur batteries (LSBs) and lithium-ion batteries (LiBs). In LSBs, TTE plays a crucial role in reducing the solubility of intermediate lithium polysulfides, thereby preventing the polysulfide shuttle (PSS) effect and improving battery performance. Recent research suggests that TTE can also lead to the formation of a compact and uniform surface layer on the lithium anode when used as an additive, which improves the efficiency and stability of Li-S batteries. In LiBs, TTE acts as a cosolvent, reducing the viscosity of the electrolyte and enabling the use of lower concentrations of lithium salt without compromising ionic conductivity. Additionally, TTE has been shown to help form a stable, conductive solid electrolyte interphase (SEI) on both graphite anodes and NMC cathodes, thereby improving the overall electrochemical performance of the battery.

Pictograms

Flame

Signal Word

Warning

Hazard Statements

Hazard Classifications

Flam. Liq. 3

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

80.6 °F - closed cup

Flash Point(C)

27 °C - closed cup


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Partially Fluorinated Ether as an Electrolyte Additive to Modify Electrode Surface and Suppress Dissolution of Polysulfides in Li-S Batteries
Qian, Feng
Electrochemical Energy Technology , 4 (2018)
Fluoro-Ether as a Bifunctional Interphase Electrolyte Additive with Graphite/LiNi0.5Co0.2Mn0.3O2 Full Cell
[3]Heng, et al.
ACS Applied Energy Materials, 2, 6404-6416 (2019)
Synthesis and electrochemical properties of partially fluorinated ether solvents for lithiumsingle bondsulfur battery electrolytes
Yue Zheng, et al.
Journal of Power Sources, 401, 271-277 (2018)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service