809063

Sodium 1-Phenoxy-methanesulfinate

• Empirical Formula (Hill Notation): C₇H₇NaO₃S
• Molecular Weight: 194.18
• UNSPSC Code: 12352200
• PubChem Substance ID: 329769135
• NACRES: NA.22
• Form: powder or crystals

Properties

• form: powder or crystals
• Quality Segment: 100
• reaction suitability: reaction type: C-C Bond Formation, reaction type: C-H Activation, reagent type: catalyst
• functional group: phenoxy, sulfinic acid
• SMILES string: O=S(O[Na])COC1=CC=CC=C1
• InChI: 1S/C7H8O3S.Na/c8-11(9)6-10-7-4-2-1-3-5-7;/h1-5H,6H2,(H,8,9);/q;+1/p-1
• InChI key: KITYKPJDXMLWTO-UHFFFAOYSA-M

Description

General description

Sodium 1-Phenoxy-methanesulfinate is a sulfinate reagent bearing a phenoxy moiety.

Application

The following Baran Sulfinate is a part of a toolbox of diversification reagents which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Other Notes

Diversinates^™: Any-Stage Functionalization of (Hetero)aromatic Scaffolds

Legal Information

Diversinates is a trademark of Sigma-Aldrich Co. LLC

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302,H315,H319,H335
• pcodes: P261 - P264 - P271 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable