673307
Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate
Synonym(s):
(Cyclopentadienyltris(acetonitrile)ruthenium hexafluorophosphate, Tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate
About This Item
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form
solid
reaction suitability
core: ruthenium
reagent type: catalyst
storage temp.
2-8°C
SMILES string
[Ru+].CC#N.CC#N.CC#N.[CH]1[CH][CH][CH][CH]1.F[P-](F)(F)(F)(F)F
InChI
1S/C5H5.3C2H3N.F6P.Ru/c1-2-4-5-3-1;3*1-2-3;1-7(2,3,4,5)6;/h1-5H;3*1H3;;/q;;;;-1;+1
InChI key
HJQVFVSAQOQXRG-UHFFFAOYSA-N
Application
- Regioselective and stereoselective dehydrative allylation of nucleophiles
- O-H Insertion and condensation reactions
- Hydrosilylation
- Decarboxylative allylic etherification
- Claisen rearrangement of unactivated allyl vinyl ethers
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
Certificates of Analysis (COA)
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The Herzon group has developed highly active catalysts for the anti-Markovnikov hydration and reductive hydration of terminal alkynes to form aldehydes and linear alcohols, respectively.
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