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Assay
97%
mp
88-95 °C (lit.)
SMILES string
Cc1cc(Br)cnc1N
InChI
1S/C6H7BrN2/c1-4-2-5(7)3-9-6(4)8/h2-3H,1H3,(H2,8,9)
InChI key
KBLGGRWUEVCNPY-UHFFFAOYSA-N
General description
2-Amino-5-bromo-3-methylpyridine can be prepared from 2-amino-3-methylpyridine, via bromination.
Application
2-Amino-5-bromo-3-methylpyridine may be used to synthesize:
- 5-bromo-2-chloro-3-methylpyridine
- 2-azidopyridine 1-oxide
- 2-amino-5-bromo-3-methylpyridine 1-oxide
- 2,5-dibromo-3-methyl pyridine
- ethyl-3,6-dibromo-8-methylimidazo[1,2-a]pyridine-2-carboxylate
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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Microwave-Assisted One-Pot Synthesis of Substituted 3-Bromoimidazo [1, 2-a] pyridines and Imidazoheterocycles.
Journal of Heterocyclic Chemistry, 51(5), 1509-1515 (2014)
Ring contraction of 2-azidopyridine 1-oxides and related compounds. 2-Cyano-1-hydroxypyrroles and-imidazoles.
Journal of the American Chemical Society, 98(6), 1478-1486 (1976)
Synthesis of the grass alkaloid perlolidine through a pyridyne cyclisation reaction.
Indian J. Chem. B, 40(11), 1129-1131 (2001)
2, 5-and 5, 6-Dihalonicotinic acids and their precursors.
Journal of Chemical and Engineering Data, 15(4), 590-591 (1970)
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