120227
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
95%
Synonym(s):
Hantzsch ester
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All Photos(4)
About This Item
Empirical Formula (Hill Notation):
C13H19NO4
CAS Number:
Molecular Weight:
253.29
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
95%
form
solid
mp
178-183 °C (lit.)
solubility
organic solvents: soluble
SMILES string
CCOC(=O)C1=C(C)NC(C)=C(C1)C(=O)OCC
InChI
1S/C13H19NO4/c1-5-17-12(15)10-7-11(13(16)18-6-2)9(4)14-8(10)3/h14H,5-7H2,1-4H3
InChI key
LJXTYJXBORAIHX-UHFFFAOYSA-N
Related Categories
General description
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate is often used as a building block in organic synthesis for the preparation of various biologically active compounds.
Application
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate (DTP) was used to study the mechanism of electrochemical oxidation of DTP in ethanol/water solutions on a glassy carbon electrode.
Used as a hydrogen source in organocatalytic reductive amination and conjugate reduction.
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Mechanistic Aspects of the Electrochemical Oxidation of Diethyl 1, 4-Dihydro-2, 6-dimethyl-3, 5-pyridinedicarboxylate on a Glassy Carbon Electrode.
Montoya MR, et al.
Electroanalysis, 11(6), 1241-1244 (1999)
Diethyl 1, 4-Dihydro-2, 6-dimethyl-3, 5-Pyridinedicarboxylate
Bechara, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis, 1-12 (2001)
M Mamadiev et al.
Voprosy meditsinskoi khimii, 29(2), 83-89 (1983-03-01)
Appearance of cadaverine deaminating activity in mitochondrial fractions of liver and kidney of rabbits with experimental alimentary hypercholesterolaemia was prevented by an antioxant diludin (2,6-dimethyl-3,5-diethoxycarbonyl-1,4-dihydropyridine) which also decreased the abnormally elevated AMP-deaminating activity and elevated the decreased monoamine oxidase activity
M V Bilenko et al.
Biulleten' eksperimental'noi biologii i meditsiny, 96(9), 8-11 (1983-09-01)
Prophylactic injection of the natural antioxidant alpha-tocopherol and synthetic antioxidants ionol, diludin and 6-mercurascan prevented the development of lesions during acute renal ischemia and subsequent reperfusion. Ionol proved more effective on intraperitoneal injection than on intragastric route of administration. It
[Geroprotective activity of 2,6-dimethyl-3,5-diethoxycarbonyl-l,4-dihydropyridine].
N M Emanuél' et al.
Doklady Akademii nauk SSSR, 284(5), 1271-1274 (1985-01-01)
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