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35800

Supelco

Biphenyl

PESTANAL®, analytical standard

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About This Item

Linear Formula:
C6H5C6H5
CAS Number:
Molecular Weight:
154.21
Beilstein:
1634058
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

vapor density

5.31 (vs air)

vapor pressure

9.46 mmHg ( 115 °C)

product line

PESTANAL®

autoignition temp.

1004 °F

shelf life

limited shelf life, expiry date on the label

expl. lim.

0.6 %, 111 °F
5.8 %, 166 °F

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

bp

255 °C (lit.)

mp

68-70 °C (lit.)

application(s)

agriculture
environmental

format

neat

SMILES string

c1ccc(cc1)-c2ccccc2

InChI

1S/C12H10/c1-3-7-11(8-4-1)12-9-5-2-6-10-12/h1-10H

InChI key

ZUOUZKKEUPVFJK-UHFFFAOYSA-N

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Application

Biphenyl may also serve as a polymerizable electrolyte additive for overcharge protection of lithium ion batteries.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 2

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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Electrochemical behavior of biphenyl as polymerizable additive for overcharge protection of lithium ion batteries
Xiao L, et al.
Electrochimica Acta, 49, 4189-4196 (2004)
Xiaofeng Chen et al.
The Journal of organic chemistry, 77(17), 7572-7578 (2012-08-07)
A highly efficient cross-coupling of diarylborinic acids and anhydrides with aryl chlorides and bromides has been effected by using a palladium catalyst system co-supported by a strong σ-donor N-heterocyclic carbene (NHC), N,N'-bis(2,6-diisopropylphenyl) imidazol-2-ylidene, and a strong π-acceptor phosphite, triphenylphosphite, in
Yang Ou et al.
Chemical communications (Cambridge, England), 49(33), 3473-3475 (2013-03-22)
A novel A21-CuI catalyzed direct nitrogenation of biphenyl halides for the direct synthesis of carbazoles via a direct C-H amination process has been developed. A recyclable and inexpensive Cu-catalyst was successfully employed in N-heterocyclic compound synthesis via tandem azidation and
Susan L Zultanski et al.
Journal of the American Chemical Society, 135(2), 624-627 (2013-01-04)
The first Suzuki cross-couplings of unactivated tertiary alkyl electrophiles are described. The method employs a readily accessible catalyst (NiBr(2)·diglyme/4,4'-di-tert-butyl-2,2'-bipyridine, both commercially available) and represents the initial example of the use of a group 10 catalyst to cross-couple unactivated tertiary electrophiles
Ondrej Uhlik et al.
PloS one, 7(7), e40653-e40653 (2012-07-19)
Bacteria were identified associated with biodegradation of aromatic pollutants biphenyl, benzoate, and naphthalene in a long-term polychlorinated biphenyl- and polyaromatic hydrocarbon-contaminated soil. In order to avoid biases of culture-based approaches, stable isotope probing was applied in combination with sequence analysis

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