Skip to Content
Merck
All Photos(2)

Documents

87651

Sigma-Aldrich

Tetrakis[tris(dimethylamino)phosphoranylidenamino]phosphonium chloride

95%

Synonym(s):

Phosphazenium chloride

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
[[(CH3)2N]3P=N]4PCl
CAS Number:
122951-89-7
Molecular Weight:
775.26
MDL number:
MFCD00171708
UNSPSC Code:
12352101
PubChem Substance ID:
57653258
NACRES:
NA.22

Assay

95%

form

crystals

mp

251 °C (dec.) (lit.)

storage temp.

2-8°C

SMILES string

[Cl-].CN(C)P(=N[P+](N=P(N(C)C)(N(C)C)N(C)C)(N=P(N(C)C)(N(C)C)N(C)C)N=P(N(C)C)(N(C)C)N(C)C)(N(C)C)N(C)C

InChI

1S/C24H72N16P5.ClH/c1-29(2)42(30(3)4,31(5)6)25-41(26-43(32(7)8,33(9)10)34(11)12,27-44(35(13)14,36(15)16)37(17)18)28-45(38(19)20,39(21)22)40(23)24;/h1-24H3;1H/q+1;/p-1

InChI key

NYTYWTQXLWNFFQ-UHFFFAOYSA-M

Looking for similar products? Visit Product Comparison Guide

Application

Tetrakis[tris(dimethylamino)phosphoranylidenamino]phosphonium chloride can be used:
  • As a lipophilic additive in the pH-responsive polymers and solvent-processible polymer membranes.
  • To prepare tetrakis[tris(dimethylamino)phosphoranylidenamino] phosphonium hydroxide, which acts as a basic catalyst for the ring-opening polymerization of siloxanes.

Other Notes

Extremely stable, lipophilic PTC; Selective O-methylation of ketone enolates

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

E.V. Dehmlow et al.
J. Chem. Res. Synop., 224-224 (1989)
Ring-opening polymerization of siloxanes using phosphazene base catalysts
Hupfield PC and Taylor RG
Journal of Inorganic and Organometallic Polymers and Materials, 9(1), 17-34 (1999)
Potentiometric pH response of polymer membranes incorporated with ion-exchangers
Kim MH, et al.
Analytical Sciences, 17(8), 995-997 (2001)
E.V. Dehmlow et al.
Zeitschrift fur Naturforschung, B: Chemical Sciences, 45, 409-409 (1990)
Solvent-processible polymer membrane-based liquid junction-free reference electrode
Lee HJ, et al.
Analytical Chemistry, 70(16), 3377-3383 (1998)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service