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Key Documents

721611

Sigma-Aldrich

Palladium pivalate

97%

Synonym(s):

2,2-Dimethylpropanoic acid palladium(II) salt

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About This Item

Empirical Formula (Hill Notation):
C10H18O4Pd
CAS Number:
Molecular Weight:
308.67
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

form

solid

reaction suitability

core: palladium
reaction type: C-H Activation
reagent type: catalyst

mp

230-232 °C

SMILES string

CC(C)(C)C(=O)O[Pd]OC(=O)C(C)(C)C

InChI

1S/2C5H10O2.Pd/c2*1-5(2,3)4(6)7;/h2*1-3H3,(H,6,7);/q;;+2/p-2

InChI key

PAGZTSLSNQZYEV-UHFFFAOYSA-L

Application

Catalyst for:
  • Aerobic cyclization of acrylic acid with alkenes
  • Benzylation of heterocycles with benzyl chlorides
  • Intramolecular direct arylation reactions
  • Regioselective oxidative arene cross-coupling

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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