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715131

Sigma-Aldrich

Dichlorodi-μ-chlorobis[(1,2,3,6,7,8-η-2,7-dimethyl-2,6-octadiene-1,8-diyl]diruthenium(IV)

97%

Synonym(s):

Tetrachlorobis(2,7-dimethyl-2,6-octadienylene)diruthenium

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About This Item

Empirical Formula (Hill Notation):
C20H32Cl4Ru2
CAS Number:
Molecular Weight:
616.42
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

form

powder

reaction suitability

core: ruthenium
reagent type: catalyst

mp

193-202 °C (dec.)

SMILES string

Cl[Ru]Cl.Cl[Ru]Cl.[CH2][C](C)[CH]CC[CH][C]([CH2])C.[CH2][C](C)[CH]CC[CH][C]([CH2])C

InChI

1S/2C10H16.4ClH.2Ru/c2*1-9(2)7-5-6-8-10(3)4;;;;;;/h2*7-8H,1,3,5-6H2,2,4H3;4*1H;;/q;;;;;;2*+2/p-4

InChI key

UILPCDNRMPZVBB-UHFFFAOYSA-J

Application

Catalyst for:
  • Selective estragole to transanethole isomerization
  • Regioselective alkylation of indoles with terminal alkynes
  • Diyne polycyclotrimerization
  • Deprotection of N-allylic amines
  • Ring-opening metathesis polymerization of norbornene
  • Polymerization of cycloalkenes and norbornene

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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