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Sigma-Aldrich

N1-(3-Trimethoxysilylpropyl)diethylenetriamine

technical grade

Synonym(s):

2-[2-(3-Trimethoxysilylpropylamino)ethylamino]ethylamine, 3-[2-(2-Aminoethylamino)ethylamino]propyltrimethoxysilane

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About This Item

Linear Formula:
(CH3O)3Si(CH2)3NHCH2CH2NHCH2CH2NH2
CAS Number:
35141-30-1
Molecular Weight:
265.43
Beilstein:
8421470
MDL number:
MFCD00069173
UNSPSC Code:
12352103
PubChem Substance ID:
24865858
NACRES:
NA.22
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grade

technical grade

vapor pressure

1 mmHg ( 20 °C)

form

liquid

refractive index

n20/D 1.459 (lit.)

bp

114-118 °C/2 mmHg (lit.)

density

1.03 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CO[Si](CCCNCCNCCN)(OC)OC

InChI

1S/C10H27N3O3Si/c1-14-17(15-2,16-3)10-4-6-12-8-9-13-7-5-11/h12-13H,4-11H2,1-3H3

InChI key

NHBRUUFBSBSTHM-UHFFFAOYSA-N

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Application

N1-(3-Trimethoxysilylpropyl)diethylenetriamine (TRI-silane) can be used as a grafting agent to incorporate amine functional group onto the surface of various ordered mesoporous silica. It can be also used in CO2 capture applications.[1][2][3]

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H315,H317,H318,H332,H412

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

204.8 °F

Flash Point(C)

96 °C

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX1748
MKCW3181
MKCS8766
MKCR1525
MKCP8868

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Modeling adsorption of CO2 on amine-functionalized mesoporous silica. 2: Kinetics and breakthrough curves
S-G Rodrigo and Sayari A
Chemical Engineering Journal, 161(1-2), 182-190 (2010)
Modeling CO2 adsorption on amine-functionalized mesoporous silica: 1. A semi-empirical equilibrium model
S-G, Rodrigo, et al.
Chemical Engineering Journal, 161(1-2), 173-181 (2010)
Mariusz Barczak et al.
Carbohydrate polymers, 247, 116747-116747 (2020-08-25)
Iron/silica core-shell microparticles (IMPs) were functionalized by different functional groups including amine, glycidoxy, phenyl, and thiocyanate. Many of the IMPs modifications are reported for the first time. The resulting surface chemistry turned out to affect the properties of magnetic alginate
N 1-(3-Trimethoxysilylpropyl) diethylenetriamine grafted KIT-6 for CO2/N2 selective separation
Kishor, Rupak and Ghoshal, Aloke Kumar
Royal Society of Chemistry Advances, 6(2), 898-909 (2016)
JinHyeong Lee et al.
Scientific reports, 10(1), 4882-4882 (2020-03-19)
In this study, the influence of drying conditions on amine (-NH3) functionalization of graphene oxide (GO) was evaluated, and the hexavalent chromium (Cr(VI)) adsorption efficiency of the prepared materials was compared. 3-[2-(2-aminoehtylamino) ethylamino]propyl-trimethoxysilane (3N) was used for amine functionalization. The
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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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