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Sigma-Aldrich

Rhodium(III) nitrate solution

~10 % (w/w) (Rh in >5 wt. % HNO3)

Synonym(s):

Aqueous rhodium nitrate, Rhodium trinitrate, Rhodium(3+)trinitrate

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About This Item

Linear Formula:
Rh(NO3)3
Molecular Weight:
288.92
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

form

liquid

concentration

≥5.0% (NaOH basis (wt% HNO3, titration))
~10 % (w/w) (Rh in >5 wt. % HNO3)

density

1.41 g/mL at 25 °C

SMILES string

[Rh]

InChI

1S/Rh

InChI key

MHOVAHRLVXNVSD-UHFFFAOYSA-N

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Application

  • The saga of rhodium (III) nitrate complexes and their speciation in solution: An integrated experimental and quantum chemical study of rhodium(III) nitrate complexes in solution (SN Vorobyeva et al., 2022).

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Inhalation - Eye Dam. 1 - Met. Corr. 1 - Ox. Liq. 3 - Skin Corr. 1A

Supplementary Hazards

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Dong Jin Lee et al.
Angewandte Chemie (International ed. in English), 54(46), 13715-13718 (2015-09-18)
A new type of intermolecular rhodium(II)-catalyzed [5+3] cycloaddition has been developed. This higher-order cycloaddition between pyridinium zwitterion 1,5-dipole equivalents and enol diazoacetates enables the formation of eight-membered heterocyclic skeletons, which are otherwise difficult to construct. The optimized cycloaddition occurs efficiently under
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Pablo E Guzmán et al.
Angewandte Chemie (International ed. in English), 53(48), 13083-13087 (2014-10-01)
A regio-, diastereo-, and enantioselective [4+3] cycloaddition between vinylcarbenes and dienes has been achieved using the dirhodium tetracarboxylate catalyst [Rh2(S-BTPCP)4]. This methodology provides facile access to 1,4-cycloheptadienes that are regioisomers of those formed from the tandem cyclopropanation/Cope rearrangement reaction of
Chumin Zhao et al.
Medical physics, 42(11), 6294-6308 (2015-11-02)
Large area x-ray imagers based on complementary metal-oxide-semiconductor (CMOS) active pixel sensor (APS) technology have been proposed for various medical imaging applications including digital breast tomosynthesis (DBT). The low electronic noise (50-300 e-) of CMOS APS x-ray imagers provides a
Malene Outzen et al.
Nutrients, 7(1), 608-624 (2015-01-20)
Selenium status of the Danish population is below that assumed optimal for the suggested protective effects against chronic diseases, including certain cancers. Fish and shellfish are important dietary sources of selenium in Denmark. We investigated the effect of increased fish

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