Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

692492

Sigma-Aldrich

(R)-RuCl[(p-cymene)(BINAP)]Cl

Synonym(s):

Chloro[(R)-(+)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl](p-cymene)ruthenium(II) chloride

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
[C54H46ClP2Ru]+Cl-
CAS Number:
145926-28-9
Molecular Weight:
928.87
MDL number:
MFCD00134456
UNSPSC Code:
12352005
PubChem Substance ID:
329761502
NACRES:
NA.22

form

powder

functional group

phosphine

storage temp.

2-8°C

SMILES string

[Cl-].Cl[Ru+].C[C]1[CH][CH][C]([CH][CH]1)C(C)C.c2ccc(cc2)P(c3ccccc3)c4ccc5ccccc5c4-c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9

InChI

1S/C44H32P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-32H;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

InChI key

WNHLGYRPKARUHY-UHFFFAOYSA-L

Related Categories

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCS0544
MKCK3103
MKBV1437V
MKAA4640
06926HJ

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 2

1 of 2

(R)-BINAP

Sigma-Aldrich

693065

(R)-BINAP

(S)-BINAP

Sigma-Aldrich

693057

(S)-BINAP

Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service